| blob | 143fb5b0a479aa8dc1043ace95445591ae44fa09 |
1 #Equations
3 {1} NO2 + hv = NO + O3P : 6.69e-1*(SUN/60.0e0);
4 {2} O3P + O2 + AIR = O3 : ARR(5.68e-34,0.0e0,-2.80e0);
5 {3} O3P + O3 = 2O2 : ARR(8.00e-12,2060.0e0,0.0e0);
6 {4} O3P + NO + AIR = NO2 : ARR(1.00e-31,0.0e0,-1.60e0);
7 {5} O3P + NO2 = NO : ARR(6.50e-12,-120.0e0,0.0e0);
8 {6} O3P + NO2 = NO3 : FALL(9.00e-32,0.0e0,-2.00e0,2.20e-11,0.0e0,0.0e0,0.80e0);
9 {7} O3 + NO = NO2 : ARR(1.80e-12,1370.0e0,0.0e0);
10 {8} O3 + NO2 = NO3 : ARR(1.40e-13,2470.0e0,0.0e0);
11 {9} NO + NO3 = 2NO2 : ARR(1.80e-11,-110.0e0,0.0e0);
12 {10} NO + NO + O2 = 2NO2 : ARR(3.30e-39,-530.0e0,0.0e0);
13 {11} NO2 + NO3 = N2O5 : FALL(2.80e-30,0.0e0,-3.50e0,2.00e-12,0.0e0,0.20e0,0.45e0);
14 {12} N2O5 = NO2 + NO3 : FALL(1.e-3,11000.0e0,-3.5e0,9.7e+14,11080.0e0,0.1e0,0.45e0);
15 {13} N2O5 + H2O = 2HNO3 : (2.60e-22);
16 {14} NO2 + NO3 = NO + NO2 : ARR(4.50e-14,1260.0e0,0.0e0);
17 {15} NO3 + hv = NO : 1.59e0*(SUN/60.0e0);
18 {16} NO3 + hv = NO2 + O3P : 1.50e+1*(SUN/60.0e0);
19 {17} O3 + hv = O3P : 3.76e-2*(SUN/60.0e0);
20 {18} O3 + hv = O1D : 4.19e-3*(SUN/60.0e0);
21 {19} O1D + H2O = 2OH : (2.20e-10);
22 {20} O1D + AIR = O3P : ARR(2.09e-11,-95.0e0,0.0e0);
23 {21} OH + NO = HONO : FALL(7.00e-31,0.0e0,-2.60e0,3.60e-11,0.0e0,-0.10e0,0.60e0);
24 {22} HONO + hv = OH + NO : 1.27e-1*(SUN/60.0e0);
25 {23} HONO + hv = HO2 + NO2 : 1.60e-2*(SUN/60.0e0);
26 {24} OH + HONO = NO2 : ARR(2.70e-12,-260.0e0,0.0e0);
27 {25} OH + NO2 = HNO3 : FALL(2.43e-30, 0.0e0,-3.10e0,1.67e-11,0.0e0,-2.10e0,0.60e0);
28 {26} OH + NO3 = HO2 + NO2 : (2.00e-11);
29 {27} OH + HNO3 = NO3 : EP2(7.20e-15,-785.0e0,4.10e-16,-1440.0e0,1.90e-33,-725.0e0);
30 {28} HNO3 + hv = OH + NO2 : 5.40e-5*(SUN/60.0e0);
31 {29} OH + CO = HO2 : EP3(1.30e-13,0.0e0,3.19e-33,0.0e0);
32 {30} OH + O3 = HO2 : ARR(1.90e-12,1000.0e0,0.0e0);
33 {31} HO2 + NO = OH + NO2 : ARR(3.40e-12,-270.0e0,0.0e0);
34 {32} HO2 + NO2 = HNO4 : FALL(1.80e-31,0.0,-3.20,4.70e-12,0.0e0,0.0,0.6);
35 {33} HNO4 = HO2 + NO2 : FALL(4.10e-05,10650.0,0.0,5.7e+15,11170.0,0.0,0.5);
36 {34} HNO4 + hv = 0.61HO2 + 0.61NO2 + 0.39OH +
37 0.39NO3 : 4.69e-4*(SUN/60.0e0);
38 {35} HNO4 + OH = NO2 : ARR(1.50e-12,-360.0e0,0.0e0);
39 {36} HO2 + O3 = OH : ARR(1.40e-14,600.0e0,0.0e0);
40 {37} HO2 + HO2 = H2O2 : EP3(2.20e-13,-600.0e0,1.85e-33,-980.0e0);
41 {38} HO2 + HO2 + H2O = H2O2 : EP3(3.08e-34,-2800.0e0,2.59e-54,-3180.0e0);
42 {39} NO3 + HO2 = 0.8OH + 0.8NO2 + 0.2HNO3 : (4.00e-12);
43 {40} NO3 + NO3 = 2NO2 : ARR(8.50e-13,2450.0e0,0.0e0);
44 {41} H2O2 + hv = 2OH : 5.64e-4*(SUN/60.0e0);
45 {42} H2O2 + OH = HO2 : ARR(2.90e-12,160.0e0,0.0e0);
46 {43} OH + HO2 = H2O + O2 : ARR(4.80e-11,-250.0e0,0.0e0);
47 {44} OH + SO2 = HO2 + H2SO4 : FALL(4.00e-31,0.0e0,-3.30e0,2.00e-12,0.0e0,0.0e0,0.45e0);
48 {45} OH + H2 = HO2 : ARR(7.70e-12,2100.0e0,0.0e0);
49 {46} C_O2 + NO = NO2 + HCHO + HO2 : ARR(2.80e-12,-285.0e0,0.0e0);
50 {47} C_O2 + HO2 = COOH : ARR(3.80e-13,-780.0e0,0.0e0);
51 {48} C_O2 + NO3 = HCHO + HO2 + NO2 : (1.30e-12);
52 {49} C_O2 + C_O2 = MEOH + HCHO : ARR(2.45e-14,-710.0e0,0.0e0);
53 {50} C_O2 + C_O2 = 2HCHO + 2HO2 : ARR(5.90e-13,509.0e0,0.0e0);
54 {51} RO2_R + NO = NO2 + HO2 : ARR(2.70e-12,-360.0e0,0.0e0);
55 {52} RO2_R + HO2 = ROOH : ARR(1.90e-13,-1300.0e0,0.0e0);
56 {53} RO2_R + NO3 = NO2 + HO2 : (2.30e-12);
57 {54} RO2_R + C_O2 = HO2 + 0.75HCHO +
58 0.25MEOH : (2.00e-13);
59 {55} RO2_R + RO2_R = HO2 : (3.50e-14);
60 {56} R2O2 + NO = NO2 : ARR(2.70e-12,-360.0e0,0.0e0);
61 {57} R2O2 + HO2 = HO2 : ARR(1.90e-13,-1300.0e0,0.0e0);
62 {58} R2O2 + NO3 = NO2 : (2.30e-12);
63 {59} R2O2 + C_O2 = C_O2 : (2.00e-13);
64 {60} R2O2 + RO2_R = RO2_R : (3.50e-14);
65 {61} R2O2 + R2O2 = 2R2O2 : (0.0e0);
66 {62} RO2_N + NO = RNO3 : ARR(2.70e-12,-360.0e0,0.0e0);
67 {63} RO2_N + HO2 = ROOH : ARR(1.90e-13,-1300.0e0,0.0e0);
68 {64} RO2_N + C_O2 = HO2 + 0.25MEOH +
69 0.5MEK + 0.5PROD2 + 0.75HCHO : (2.00e-13);
70 {65} RO2_N + NO3 = NO2 + HO2 + MEK : (2.30e-12);
71 {66} RO2_N + RO2_R = HO2 + 0.5MEK +
72 0.5PROD2 : (3.50e-14);
73 {67} RO2_N + R2O2 = RO2_N : (3.50e-14);
74 {68} RO2_N + RO2_N = MEK + HO2 + PROD2 : (3.50e-14);
75 {69} CCO_O2 + NO2 = PAN : FALL(2.70e-28,0.0e0,-7.10e0,1.20e-11,0.0e0,-0.90e0,0.30e0);
76 {70} PAN = CCO_O2 + NO2 : FALL(4.90e-3,12100.0e0,0.0e0,4.0e+16,13600.0e0,0.e0,0.3e0);
77 {71} CCO_O2 + NO = C_O2 + NO2 : ARR(7.80e-12,-300.0e0,0.0e0);
78 {72} CCO_O2 + HO2 = 0.75CCO_OOH +
79 0.25CCO_OH + 0.25O3 : ARR(4.30e-13,-1040.0e0,0.0e0);
80 {73} CCO_O2 + NO3 = C_O2 + NO2 : (4.00e-12);
81 {74} CCO_O2 + C_O2 = CCO_OH + HCHO : ARR(1.80e-12,-500.0e0,0.0e0);
82 {75} CCO_O2 + RO2_R = CCO_OH : (7.50e-12);
83 {76} CCO_O2 + R2O2 = CCO_O2 : (7.50e-12);
84 {77} CCO_O2 + RO2_N = CCO_OH + PROD2 : (7.50e-12);
85 {78} CCO_O2 + CCO_O2 = 2C_O2 : ARR(2.90e-12,-500.0e0,0.0e0);
86 {79} RCO_O2 + NO2 = PAN2 : ARR(1.20e-11,0.0e0,-0.90e0);
87 {80} PAN2 = RCO_O2 + NO2 : ARR(2.00e+15,12800.0e0,0.0e0);
88 {81} RCO_O2 + NO = NO2 + CCHO + RO2_R : ARR(1.25e-11,-240.0e0,0.0e0);
89 {82} RCO_O2 + HO2 = 0.75RCO_OOH +
90 0.25RCO_OH + 0.25O3 : ARR(4.30e-13,-1040.0e0,0.0e0);
91 {83} RCO_O2 + NO3 = NO2 + CCHO + RO2_R : (4.00e-12);
92 {84} RCO_O2 + C_O2 = RCO_OH + HCHO : ARR(1.80e-12,-500.0e0,0.0e0);
93 {85} RCO_O2 + RO2_R = RCO_OH : (7.50e-12);
94 {86} RCO_O2 + R2O2 = RCO_O2 : (7.50e-12);
95 {87} RCO_O2 + RO2_N = RCO_OH + PROD2 : (7.50e-12);
96 {88} RCO_O2 + CCO_O2 = C_O2 + CCHO + RO2_R : ARR(2.90e-12,-500.0e0,0.0e0);
97 {89} RCO_O2 + RCO_O2 = 2CCHO + 2RO2_R : ARR(2.90e-12,-500.0e0,0.0e0);
98 {90} BZCO_O2 + NO2 = PBZN : (1.37e-11);
99 {91} PBZN = BZCO_O2 + NO2 : ARR(7.90e+16,14000.0e0,0.0e0);
100 {92} BZCO_O2 + NO = NO2 + BZ_O + R2O2 : ARR(1.25e-11,-240.0e0,0.0e0);
101 {93} BZCO_O2 + HO2 = 0.75RCO_OOH +
102 0.25RCO_OH + 0.25O3 : ARR(4.30e-13,-1040.0e0,0.0e0);
103 {94} BZCO_O2 + NO3 = NO2 + BZ_O + R2O2 : (4.00e-12);
104 {95} BZCO_O2 + C_O2 = RCO_OH + HCHO : ARR(1.80e-12,-500.0e0,0.0e0);
105 {96} BZCO_O2 + RO2_R = RCO_OH : (7.50e-12);
106 {97} BZCO_O2 + R2O2 = BZCO_O2 : (7.50e-12);
107 {98} BZCO_O2 + RO2_N = RCO_OH + PROD2 : (7.50e-12);
108 {99} BZCO_O2 + CCO_O2 = C_O2 + BZ_O + R2O2 : ARR(2.90e-12,-500.0e0,0.0e0);
109 {100} BZCO_O2 + RCO_O2 = CCHO + RO2_R +
110 BZ_O + R2O2 : ARR(2.90e-12,-500.0e0,0.0e0);
111 {101} BZCO_O2 + BZCO_O2 = 2BZ_O + 2R2O2: ARR(2.90e-12,-500.0e0,0.0e0);
112 {102} MA_RCO3 + NO2 = MA_PAN : ARR(1.20e-11,0.0e0,-0.90e0);
113 {103} MA_PAN = MA_RCO3 + NO2 : ARR(1.60e+16,13486.0e0,0.0e0);
114 {104} MA_RCO3 + NO = NO2 + HCHO + CCO_O2 : ARR(1.25e-11,-240.0e0,0.0e0);
115 {105} MA_RCO3 + HO2 = 0.75RCO_OOH +
116 0.25RCO_OH + 0.25O3 : ARR(4.30e-13,-1040.0e0,0.0e0);
117 {106} MA_RCO3 + NO3 = NO2 + HCHO + CCO_O2 : (4.00e-12);
118 {107} MA_RCO3 + C_O2 = RCO_OH + HCHO : ARR(1.80e-12,-500.0e0,0.0e0);
119 {108} MA_RCO3 + RO2_R = RCO_OH : (7.50e-12);
120 {109} MA_RCO3 + R2O2 = MA_RCO3 : (7.50e-12);
121 {110} MA_RCO3 + RO2_N = 2RCO_OH : (7.50e-12);
122 {111} MA_RCO3 + CCO_O2 = C_O2 + HCHO +
123 CCO_O2 : ARR(2.90e-12,-500.0e0,0.0e0);
124 {112} MA_RCO3 + RCO_O2 = HCHO + CCO_O2 +
125 CCHO + RO2_R : ARR(2.90e-12,-500.0e0,0.0e0);
126 {113} MA_RCO3 + BZCO_O2 = HCHO + CCO_O2 +
127 BZ_O + R2O2 : ARR(2.90e-12,-500.0e0,0.0e0);
128 {114} MA_RCO3 + MA_RCO3 = 2HCHO + 2CCO_O2 : ARR(2.90e-12,-500.0e0,0.0e0);
129 {115} TBU_O + NO2 = RNO3 : (2.40e-11);
130 {116} TBU_O = ACET + C_O2 : ARR(7.50e+14,8152.0e0,0.0e0);
131 {117} BZ_O + NO2 = NPHE : ARR(2.30e-11,-150.0e0,0.0e0);
132 {118} BZ_O + HO2 = PHEN : ARR(1.90e-13,-1300.0e0,0.0e0);
133 {119} BZ_O = PHEN : (1.00e-03);
134 {120} BZNO2_O + NO2 = 2XN + 6XC: ARR(7.50e+14,8152.0e0,0.0e0);
135 {121} BZNO2_O + HO2 = NPHE : ARR(2.30e-11,-150.0e0,0.0e0);
136 {122} BZNO2_O = NPHE : ARR(1.90e-13,-1300.0e0,0.0e0);
137 {123} HCHO + hv = 2HO2 + CO : 2.32e-3*(SUN/60.0e0);
138 {124} HCHO + hv = CO : 3.15e-3*(SUN/60.0e0);
139 {125} HCHO + OH = HO2 + CO : ARR(8.60e-12,-20.0e0,0.0e0);
140 {126} HCHO + HO2 = HOCOO : ARR(9.70e-15,-625.0e0,0.0e0);
141 {127} HOCOO = HO2 + HCHO : ARR(2.40e+12,7000.0e0,0.0e0);
142 {128} HOCOO + NO = HCOOH + NO2 + HO2 : ARR(2.80e-12,-285.0e0,0.0e0);
143 {129} HCHO + NO3 = HNO3 + HO2 + CO : ARR(2.00e-12,2431.0e0,0.0e0);
144 {130} CCHO + OH = CCO_O2 : ARR(5.60e-12,-310.0e0,0.0e0);
145 {131} CCHO +hv = CO + HO2 + C_O2 : 4.16e-4*(SUN/60.0e0);
146 {132} CCHO + NO3 = HNO3 + CCO_O2 : ARR(1.40e-12,1860.0e0,0.0e0);
147 {133} RCHO + OH = 0.034RO2_R + 0.001RO2_N +
148 0.965RCO_O2 + 0.034CO+ 0.034CCHO : (2.00e-11);
149 {134} RCHO + hv = CCHO + RO2_R + CO + HO2 : 1.40e-3*(SUN/60.0e0);
150 {135} RCHO + NO3 = HNO3 + RCO_O2 : ARR(1.40e-12,1771.0e0,0.0e0);
151 {136} ACET + OH = HCHO + CCO_O2 + R2O2 : ARR(1.10e-12,520.0e0,0.0e0);
152 {137} ACET + hv = CCO_O2 + C_O2 : 4.16e-5*(SUN/60.0e0);
153 {138} MEK + OH = 0.37RO2_R + 0.042RO2_N +
154 0.616R2O2+ 0.492CCO_O2 +
155 0.096RCO_O2 + 0.115HCHO +
156 0.482CCHO + 0.37RCHO : ARR(1.30e-12,25.0e0,2.0e0);
157 {139} MEK + hv = CCO_O2 + CCHO + RO2_R : 9.49e-4*(1.50e-1*SUN/60.0e0);
158 {140} MEOH + OH = HCHO + HO2 : ARR(3.10e-12,360.0e0,2.0e0);
159 {141} COOH + OH = 0.35HCHO + 0.35OH +
160 0.65C_O2 : ARR(2.90e-12,-190.0e0,0.0e0);
161 {142} COOH + hv = HCHO + HO2 + OH : 3.94e-4*(SUN/60.0e0);
162 {143} ROOH + OH = RCHO + 0.34RO2_R +
163 0.66OH : (1.10e-11);
164 {144} ROOH + hv = RCHO + HO2 + OH : 3.94e-4*(SUN/60.0e0);
165 {145} GLY + hv = 2CO+ 2HO2 : 8.93e-3*(SUN/60.0e0);
166 {146} GLY + hv = HCHO + CO : 1.81e-1*(6.00e-3*SUN/60.0e0);
167 {147} GLY + OH = 0.63HO2 + 1.26CO+
168 0.37RCO_O2 : (1.10e-11);
169 {148} GLY + NO3 = HNO3 + 0.63HO2 +
170 1.26CO+ 0.37RCO_O2 : ARR(2.80e-12,2376.0e0,0.0e0);
171 {149} MGLY + hv = HO2 + CO + CCO_O2 : 1.10e-2*(SUN/60.0e0);
172 {150} MGLY + OH = CO + CCO_O2 : 1.50e-11;
173 {151} MGLY + NO3 = HNO3 + CO + CCO_O2 : ARR(1.40e-12,1895.0e0,0.0e0);
174 {152} BACL + hv = 2CCO_O2 : 1.90e-2*(SUN/60.0e0);
175 {153} PHEN + OH = 0.24BZ_O + 0.76RO2_R +
176 0.23GLY : (2.63e-11);
177 {154} PHEN + NO3 = HNO3 + BZ_O : (3.78e-12);
178 {155} CRES + OH = 0.24BZ_O + 0.76RO2_R +
179 0.23MGLY : (4.20e-11);
180 {156} CRES + NO3 = HNO3 + BZ_O : (1.37e-11);
181 {157} NPHE + NO3 = HNO3 + BZNO2_O : (3.78e-12);
182 {158} BALD + OH = BZCO_O2 : (1.29e-11);
183 {159} BALD + hv = 7XC: 6.22e-2*(5.00e-2*SUN/60.0e0);
184 {160} BALD + NO3 = HNO3 + BZCO_O2 : ARR(1.40e-12,1872.0e0,0.0e0);
185 {161} METHACRO + OH = 0.5RO2_R + 0.416CO+
186 0.084HCHO + 0.416MEK +
187 0.084MGLY + 0.5MA_RCO3 : ARR(1.86e-11,-176.0e0,0.0e0);
188 {162} METHACRO + O3 = 0.008HO2 + 0.1RO2_R +
189 0.208OH + 0.1RCO_O2 + 0.45CO+
190 0.2HCHO + 0.9MGLY + 0.333HCOOH : ARR(1.36e-15,2114.0e0,0.0e0);
191 {163} METHACRO + NO3 = 0.5HNO3 + 0.5RO2_R +
192 0.5CO+ 0.5MA_RCO3 : ARR(1.50e-12,1726.0e0,0.0e0);
193 {164} METHACRO + O3P = RCHO : (6.34e-12);
194 {165} METHACRO + hv = 0.34HO2 + 0.33RO2_R +
195 0.33OH + 0.67CCO_O2 + 0.67CO+
196 0.67HCHO + 0.33MA_RCO3 : 3.32e-2*(4.10e-3*SUN/60.0e0);
197 {166} MVK + OH = 0.3RO2_R + 0.025RO2_N +
198 0.675R2O2+ 0.675CCO_O2 +
199 0.3HCHO + 0.675RCHO + 0.3MGLY : ARR(4.14e-12,-453.0e0,0.0e0);
200 {167} MVK + O3 = 0.064HO2 + 0.05RO2_R +
201 0.164OH + 0.05RCO_O2 + 0.475CO+
202 0.1HCHO + 0.95MGLY + 0.351HCOOH : ARR(7.51e-16,1520.0e0,0.0e0);
203 {168} MVK + O3P = 0.45RCHO + 0.55MEK : (4.32e-12);
204 {169} MVK + hv = 0.3C_O2 + 0.7CO+ 0.7PROD2 +
205 0.3MA_RCO3 : 3.32e-2*(2.10e-3*SUN/60.0e0);
206 {170} ISOPROD + OH = 0.67RO2_R +
207 0.041RO2_N + 0.289MA_RCO3 +
208 0.336CO+ 0.055HCHO + 0.129CCHO +
209 0.013RCHO + 0.15MEK + 0.332PROD2 +
210 0.15GLY + 0.174MGLY : (6.19e-11);
211 {171} ISOPROD + O3 = 0.4HO2 + 0.048RO2_R +
212 0.048RCO_O2 + 0.285OH +
213 0.498CO+ 0.125HCHO + 0.047CCHO +
214 0.21MEK + 0.023GLY + 0.742MGLY +
215 0.1HCOOH + 0.372RCO_OH : (4.18e-18);
216 {172} ISOPROD + NO3 = 0.799RO2_R +
217 0.051RO2_N + 0.15MA_RCO3 + 0.572CO+
218 0.15HNO3 + 0.227HCHO + 0.218RCHO +
219 0.008MGLY + 0.572RNO3 : (1.00e-13);
220 {173} ISOPROD + hv = 1.233HO2 + 0.467CCO_O2 +
221 0.3RCO_O2 + 1.233CO+ 0.3HCHO +
222 0.467CCHO + 0.233MEK : 3.32e-2*(4.10e-3*SUN/60.0e0);
223 {174} PROD2 + OH = 0.379HO2 + 0.473RO2_R +
224 0.07RO2_N + 0.029CCO_O2 +
225 0.049RCO_O2 + 0.213HCHO +
226 0.084CCHO + 0.558RCHO +
227 0.115MEK + 0.329PROD2 : (1.50e-11);
228 {175} PROD2 + hv = 0.96RO2_R + 0.04RO2_N +
229 0.515R2O2+ 0.667CCO_O2 +
230 0.333RCO_O2 + 0.506HCHO +
231 0.246CCHO + 0.71RCHO : 9.49e-4*(2.00e-2*SUN/60.0e0);
232 {176} RNO3 + OH = 0.338NO2 + 0.113HO2 +
233 0.376RO2_R + 0.173RO2_N +
234 0.596R2O2+ 0.01HCHO +
235 0.439CCHO + 0.213RCHO +
236 0.006ACET + 0.177MEK +
237 0.048PROD2 + 0.31RNO3 : (7.80e-12);
238 {177} RNO3 + hv = NO2 + 0.341HO2 + 0.564RO2_R +
239 0.095RO2_N + 0.152R2O2+ 0.134HCHO +
240 0.431CCHO + 0.147RCHO + 0.02ACET +
241 0.243MEK + 0.435PROD2 : 2.35e-4*(SUN/60.0e0);
242 {178} DCB1 + OH = RCHO + RO2_R + CO : (5.00e-11);
243 {179} DCB1 + O3 = 1.5HO2 + 0.5OH +
244 1.5CO + GLY : (2.00e-18);
245 {180} DCB2 + OH = R2O2 + RCHO + CCO_O2 : (5.00e-11);
246 {181} DCB2 + hv = RO2_R + 0.5CCO_O2 + 0.5HO2 +
247 CO + R2O2 + 0.5GLY + 0.5MGLY : 2.06e-1*(3.65e-1*SUN/60.0e0);
248 {182} DCB3 + OH = R2O2 + RCHO + CCO_O2 : (5.00e-11);
249 {183} DCB3 + hv = RO2_R + 0.5CCO_O2 + 0.5HO2 +
250 CO + R2O2 + 0.5GLY + 0.5MGLY : 3.32e-2*(7.28e0*SUN/60.0e0);
251 {184} CH4 + OH = C_O2 : ARR(2.15e-12,1735.0e0,0.0e0);
252 {185} ETHENE + OH = RO2_R + 1.61HCHO +
253 0.195CCHO : ARR(1.96e-12,-438.0e0,0.0e0);
254 {186} ETHENE + O3 = 0.12OH + 0.12HO2 +
255 0.5CO+ HCHO + 0.37HCOOH : ARR(9.14e-15,2580.0e0,0.0e0);
256 {187} ETHENE + NO3 = RO2_R + RCHO : ARR(4.39e-13,2282.0e0,2.0e0);
257 {188} ETHENE + O3P = 0.5HO2 + 0.2RO2_R +
258 0.3C_O2 + 0.491CO+ 0.191HCHO +
259 0.25CCHO + 0.009GLY : ARR(1.04e-11,792.0e0,0.0e0);
260 {189} ISOPRENE + OH = 0.907RO2_R +
261 0.093RO2_N + 0.079R2O2+
262 0.624HCHO + 0.23METHACRO +
263 0.32MVK + 0.357ISOPROD : ARR(2.50e-11,-408.0e0,0.0e0);
264 {190} ISOPRENE + O3 = 0.266OH +
265 0.066RO2_R + 0.008RO2_N +
266 0.126R2O2+ 0.192MA_RCO3 +
267 0.275CO+ 0.592HCHO + 0.1PROD2 +
268 0.39METHACRO + 0.16MVK +
269 0.204HCOOH + 0.15RCO_OH : ARR(7.86e-15,1912.0e0,0.0e0);
270 {191} ISOPRENE + NO3 = 0.187NO2 +
271 0.749RO2_R + 0.064RO2_N +
272 0.187R2O2+ 0.936ISOPROD : ARR(3.03e-12,448.0e0,0.0e0);
273 {192} ISOPRENE + O3P = 0.01RO2_N +
274 0.24R2O2+ 0.25C_O2 + 0.24MA_RCO3 +
275 0.24HCHO + 0.75PROD2 : (3.60e-11);
276 {193} TERP + OH = 0.75RO2_R + 0.25RO2_N +
277 0.5R2O2+ 0.276HCHO +
278 0.474RCHO + 0.276PROD2 : ARR(1.83e-11,-449.0e0,0.0e0);
279 {194} TERP + O3 = 0.567OH + 0.033HO2 +
280 0.031RO2_R + 0.18RO2_N +
281 0.729R2O2+ 0.123CCO_O2 +
282 0.201RCO_O2 + 0.157CO+
283 0.235HCHO + 0.205RCHO + 0.13ACET +
284 0.276PROD2 + 0.001GLY + 0.031BACL +
285 0.103HCOOH + 0.189RCO_OH : ARR(1.08e-15,821.0e0,0.0e0);
286 {195} TERP + NO3 = 0.474NO2 +
287 0.276RO2_R + 0.25RO2_N +
288 0.75R2O2+ 0.474RCHO + 0.276RNO3 : ARR(3.66e-12,-175.e00,0.0e0);
289 {196} TERP + O3P = 0.147RCHO + 0.853PROD2 : (3.27e-11);
290 {197} ALK1 + OH = RO2_R + CCHO : ARR(1.37e-12,498.0e0,2.0e0);
291 {198} ALK2 + OH = 0.246OH + 0.121HO2 +
292 0.612RO2_R + 0.021RO2_N +
293 0.16CO + 0.039HCHO + 0.155RCHO +
294 0.417ACET +
295 0.248GLY + 0.121HCOOH : ARR(9.87e-12,671.0e0,0.0e0);
296 {199} ALK3 + OH = 0.695RO2_R + 0.07RO2_N +
297 0.559R2O2+ 0.236TBU_O + 0.026HCHO +
298 0.445CCHO + 0.122RCHO + 0.024ACET +
299 0.332MEK : ARR(1.019e-11,434.0e0,0.0e0);
300 {200} ALK4 + OH = 0.835RO2_R + 0.143RO2_N +
301 0.936R2O2+ 0.011C_O2 + 0.011CCO_O2 +
302 0.002CO+ 0.024HCHO + 0.455CCHO +
303 0.244RCHO + 0.452ACET + 0.11MEK +
304 0.125PROD2 : ARR(5.946e-12,91.0e0,0.0e0);
305 {201} ALK5 + OH = 0.653RO2_R + 0.347RO2_N +
306 0.948R2O2+ 0.026HCHO + 0.099CCHO +
307 0.204RCHO + 0.072ACET + 0.089MEK +
308 0.417PROD2 : ARR(1.112e-11,52.0e0,0.0e0);
309 {202} ARO1 + OH = 0.224HO2 + 0.765RO2_R +
310 0.011RO2_N + 0.055PROD2 + 0.118GLY +
311 0.119MGLY + 0.017PHEN + 0.207CRES +
312 0.059BALD + 0.491DCB1 + 0.108DCB2 +
313 0.051DCB3 : ARR(1.81e-12,-355.0e0,0.0e0);
314 {203} ARO2 + OH = 0.187HO2 + 0.804RO2_R +
315 0.009RO2_N + 0.097GLY + 0.287MGLY +
316 0.087BACL + 0.187CRES + 0.05BALD +
317 0.561DCB1 + 0.099DCB2 + 0.093DCB3 : (2.640e-11);
318 {204} OLE1 + OH = 0.91RO2_R + 0.09RO2_N +
319 0.205R2O2+ 0.732HCHO + 0.294CCHO +
320 0.497RCHO + 0.005ACET + 0.119PROD2 : ARR(7.095e-12,-451.0e0,0.0e0);
321 {205} OLE1 + O3 = 0.155OH + 0.056HO2 +
322 0.022RO2_R + 0.001RO2_N +
323 0.076C_O2 + 0.345CO+ 0.5HCHO +
324 0.154CCHO + 0.363RCHO + 0.001ACET +
325 0.215PROD2 + 0.185HCOOH +
326 0.05CCO_OH + 0.119RCO_OH : ARR(2.617e-15,1640.0e0,0.0e0);
327 {206} OLE1 + NO3 = 0.824RO2_R + 0.176RO2_N +
328 0.488R2O2+ 0.009CCHO + 0.037RCHO +
329 0.024ACET + 0.511RNO3 : ARR(4.453e-14,376.0e0,0.0e0);
330 {207} OLE1 + O3P = 0.45RCHO + 0.437MEK +
331 0.113PROD2 : ARR(1.074e-11,234.0e0,0.0e0);
332 {208} OLE2 + OH = 0.918RO2_R + 0.082RO2_N +
333 0.001R2O2+ 0.244HCHO + 0.732CCHO +
334 0.511RCHO + 0.127ACET + 0.072MEK +
335 0.061BALD + 0.025METHACRO +
336 0.025ISOPROD : ARR(1.743e-11,-384.0e0,0.0e0);
337 {209} OLE2 + O3 = 0.378OH + 0.003HO2 +
338 0.033RO2_R + 0.002RO2_N + 0.137R2O2+
339 0.197C_O2 + 0.137CCO_O2 +
340 0.006RCO_O2 + 0.265CO+ 0.269HCHO +
341 0.456CCHO + 0.305RCHO + 0.045ACET +
342 0.026MEK + 0.043PROD2 + 0.042BALD +
343 0.026METHACRO + 0.019MVK +
344 0.073HCOOH + 0.129CCO_OH +
345 0.247RCO_OH : ARR(5.022e-16,461.0e0,0.0e0);
346 {210} OLE2 + NO3 = 0.391NO2 + 0.442RO2_R +
347 0.136RO2_N + 0.711R2O2+ 0.03C_O2 +
348 0.079HCHO + 0.507CCHO + 0.151RCHO +
349 0.102ACET + 0.001MEK + 0.015BALD +
350 0.048MVK + 0.321RNO3 : (7.265e-13);
351 {211} OLE2 + O3P = 0.013HO2 + 0.012RO2_R +
352 0.001RO2_N + 0.012CO+ 0.069RCHO +
353 0.659MEK + 0.259PROD2 +
354 0.012METHACRO : (2.085e-11);