| blob | d4defe896a9b6096ffd8eb9043b5c539f4c39245 |
1 #EQUATIONS {}
2 {001:J01} NO2+hv=O3P+NO : j(Pj_no2) ;
3 {002:J02} O3+hv=O1D{+O2} : j(Pj_o31d) ;
4 {003:J03} O3+hv=O3P{+O2} : j(Pj_o33p) ;
5 {004:J04} HONO+hv=HO+NO : j(Pj_hno2) ;
6 {005:J05} HNO3+hv=HO+NO2 : j(Pj_hno3) ;
7 {006:J06} HNO4+hv=0.65 HO2+0.65 NO2+0.35 HO+0.35 NO3 : j(Pj_hno4) ;
8 {007:J07} NO3+hv=NO{+O2} : j(Pj_no3o2) ;
9 {008:J08} NO3+hv=NO2+O3P : j(Pj_no3o) ;
10 {009:J09} H2O2+hv=HO+HO : j(Pj_h2o2) ;
11 {010:J10} HCHO+hv=CO{+H2} : j(Pj_ch2om) ;
12 {011:J11} HCHO+hv=HO2+HO2+CO : j(Pj_ch2or) ;
13 {012:J12} ALD+hv=MO2+HO2+CO : j(Pj_ch3cho) ;
14 {013:J13} OP1+hv=HCHO+HO2+HO : j(Pj_ch3o2h) ;
15 {014:J14} OP2+hv=ALD+HO2+HO : j(Pj_ch3coch3) ;
16 {015:J15} PAA+hv=MO2+HO : j(Pj_ch3coo2h) ;
17 {016:J16} KET+hv=ACO3+ETHP : j(Pj_ch3coc2h5) ;
18 {017:J17} GLY+hv=0.13 HCHO+1.87 CO{+0.87 H2} : j(Pj_hcocho) ;
19 {018:J18} GLY+hv=0.45 HCHO+1.55 CO+0.80 HO2{+0.15 H2} : j(Pj_hcochob) ;
20 {019:J19} MGLY+hv=ACO3+HO2+CO : j(Pj_ch3cocho) ;
21 {020:J20} DCB+hv=HO2+TCO3 : j(Pj_hcochest) ;
22 {021:J21} ONIT+hv=0.20 ALD+0.80 KET+HO2+NO2 : j(Pj_ch3ono2) ;
23 {022:J22} MACR+hv=CO+HCHO+HO2+ACO3 : j(Pj_macr) ;
24 {023:J23} HKET+hv=HCHO+HO2+ACO3 : j(Pj_ch3coc2h5) ;
25 {024:001} O3P+M{O2}=O3 : (C_M *6.00e-34*(TEMP/300.0)**(-2.3)) ;
26 {025:002} O3P+O3=M {2O2} : ARR2( 8.00e-12 , 2060.0, TEMP) ;
27 {026:003} O1D + M = O3{+O2} : .78084*ARR2(1.8E-11,-110., TEMP);
28 {027:004} O1D + M = O3P{+O2} : .20946*ARR2( 3.20e-11 , -70.0 , TEMP ) ;
29 {028:005} O1D+H2O=HO+HO : 2.20e-10 ;
30 {029:006} O3+HO=HO2{+O2} : ARR2( 1.60e-12 , 940.0, TEMP ) ;
31 {030:007} O3+HO2=HO{+2.0 O2} : ARR2( 1.10e-14 , 500.0, TEMP ) ;
32 {031:008} HO+HO2=H2O{+O2} : ARR2( 4.80e-11 , -250.0, TEMP ) ;
33 {032:009} H2O2+HO=HO2+H2O : ARR2( 2.90e-12 , 160.0, TEMP ) ;
34 {033:010} HO2+HO2=H2O2{+O2} : (2.3e-13*EXP(600./TEMP) + 1.7e-33* C_M *EXP(1000./TEMP)) ;
35 {034:011} HO2+HO2+H2O=H2O2+H2O{+O2} : (3.22e-34* EXP(2800./TEMP)+ 2.38e-54* C_M *EXP(3200./TEMP)) ;
36 {035:012} O3P+NO=NO2 : TROE( 9.00e-32 , 1.5 , 3.00e-11 , 0.0 , TEMP, C_M) ;
37 {036:013} O3P+NO2=NO{+O2} : ARR2( 6.50e-12 , -120.0, TEMP) ;
38 {037:014} O3P+NO2=NO3 : TROE( 9.00e-32 , 2.0 , 2.20e-11 , 0.0 , TEMP, C_M) ;
39 {038:015} NO+HO=HONO : TROE( 7.00e-31 , 2.6 , 1.50e-11 , 0.5 , TEMP, C_M) ;
40 {039:016} HO+NO2=HNO3 : TROE( 2.60e-30 , 3.2 , 2.40e-11 , 1.3 , TEMP, C_M) ;
41 {040:017} HO+NO3=NO2+HO2 : 2.20e-11 ;
42 {041:018} HO2+NO=NO2+HO : ARR2( 3.70e-12 , -250.0, TEMP ) ;
43 {042:019} HO2+NO2=HNO4 : TROE( 1.80e-31 , 3.2 , 4.70e-12 , 1.4 , TEMP, C_M) ;
44 {043:020} HNO4=HO2+NO2 : TROEE( 4.76e26,10900.0, 1.80e-31 , 3.2 , 4.70e-12 , 1.4 , TEMP, C_M ) ;
45 {044:021} HO2+NO3=0.3 HNO3+0.7 NO2+0.7 HO{+O2} : 3.50e-12 ;
46 {045:022} HO+HONO=NO2+H2O : ARR2( 1.80e-11 , 390.0, TEMP ) ;
47 {046:023} HO+HNO3=NO3+H2O : k46(TEMP,C_M) ;
48 {047:024} HO+HNO4=NO2+H2O{+O2} : ARR2( 1.30e-12 , -380.0, TEMP ) ;
49 {048:025} O3+NO=NO2{+O2} : ARR2( 2.00e-12 , 1400.0, TEMP ) ;
50 {049:026} O3+NO2=NO3{+O2} : ARR2( 1.20e-13 , 2450.0, TEMP ) ;
51 {050:027} NO+NO+M{O2}=NO2+NO2 : (.20946e0*ARR2( 3.30e-39 , -530.0, TEMP )) ;
52 {051:028} NO3+NO=NO2+NO2 : ARR2( 1.50e-11 , -170.0 , TEMP) ;
53 {052:029} NO3+NO2=NO+NO2{+O2} : ARR2( 4.50e-14, 1260.0, TEMP ) ;
54 {053:030} NO3+NO2=N2O5 : TROE( 2.20e-30 , 3.9 , 1.50e-12 , 0.7 , TEMP, C_M) ;
55 {054:031} N2O5=NO2+NO3 : TROEE(3.70e26,11000.0, 2.20e-30 , 3.9 , 1.50e-12 , 0.7 , TEMP, C_M ) ;
56 {055:032} NO3+NO3=NO2+NO2{+O2} : ARR2( 8.50e-13 , 2450.0, TEMP ) ;
57 {056:033} HO+M{=H2}=H2O+HO2 : (5.31E-7*ARR2( 5.50e-12 , 2000.0, TEMP )) ;{fixed H2 (531ppb) Novelli '99}
58 {057:034} HO+SO2=SULF+HO2 : TROE( 3.00e-31 , 3.3 , 1.50e-12 , 0.0 , TEMP, C_M) ;
59 {058:035} CO+HO=HO2+CO2 : 1.5e-13 * (1.0 + 2.439e-20 * C_M) ;
60 {059:036} ISO+O3P=0.86 OLT+0.05 HCHO+0.02 HO+0.01 CO+0.13 DCB+0.28 HO2+0.15 XO2 : 6.0E-11 ;
61 {060:037} MACR+O3P=ALD : ARR2(1.59E-11,-13.0, TEMP) ;
62 {061:038} CH4+HO=MO2+H2O : (THERMAL_T2(7.44e-18, 1361.0,TEMP )) ;
63 {062:039} ETH+HO=ETHP+H2O : (THERMAL_T2(1.51e-17, 492.0,TEMP )) ;
64 {063:040} HC3+HO=0.583 HC3P+0.381 HO2+0.335 ALD+0.036 ORA1+0.036 CO+0.036 GLY+0.036 HO+0.010 HCHO+H2O : ARR2( 5.26e-12 , 260.0, TEMP ) ;
65 {064:041} HC5+HO=0.75 HC5P+0.25 KET+0.25 HO2+H2O : ARR2( 8.02e-12 , 155.0, TEMP ) ;
66 {065:042} HC8+HO=0.9511 HC8P+0.025 ALD+0.024 HKET+0.049 HO2+H2O : ARR2( 1.64e-11 , 125.0, TEMP ) ;
67 {066:043} ETE+HO=ETEP : ARR2( 1.96e-12 , -438.0, TEMP ) ;
68 {067:044} OLT+HO=OLTP : ARR2( 5.72e-12 , -500.0, TEMP ) ;
69 {068:045} OLI+HO=OLIP : ARR2( 1.33e-11 , -500.0, TEMP ) ;
70 {069:046} DIEN+HO=ISOP : ARR2( 1.48e-11 , -448.0, TEMP ) ;
71 {070:047} ISO+HO=ISOP : ARR2( 2.54e-11 , -410.0, TEMP ) ;
72 {071:048} API+HO=APIP : ARR2( 1.21e-11 , -444.0, TEMP ) ;
73 {072:049} LIM+HO=LIMP : 1.71e-10 ;
74 {073:050} TOL+HO=0.90 ADDT+0.10 XO2+0.10 HO2 : ARR2( 1.81e-12 , -355.0, TEMP ) ;
75 {074:051} XYL+HO=0.90 ADDX+0.10 XO2+0.10 HO2 : ARR2( 7.30e-12 , -355.0, TEMP ) ;
76 {075:052} CSL+HO=0.85 ADDC+0.10 PHO+0.05 HO2+0.05 XO2 : 6.00e-11 ;
77 {076:053} HCHO+HO=HO2+CO+H2O : 1.00e-11 ;
78 {077:054} ALD+HO=ACO3+H2O : ARR2( 5.55e-12 , -331.0, TEMP ) ;
79 {078:055} KET+HO=KETP+H2O : (THERMAL_T2(5.68e-18, -92.0,TEMP )) ;
80 {079:056} HKET+HO=HO2+MGLY+H2O : 3.00e-12 ;
81 {080:057} GLY+HO=HO2+2.0 CO+H2O : 1.14e-11 ;
82 {081:058} MGLY+HO=ACO3+CO+H2O : 1.72e-11 ;
83 {082:059} MACR+HO=0.51 TCO3+0.41 HKET+0.08 MGLY+0.41 CO+0.08 HCHO+0.49 HO2+0.49 XO2 : ARR2(1.86E-11, -175.0, TEMP) ;
84 {083:060} DCB+HO=0.50 TCO3+0.50 HO2+0.50 XO2+0.35 UDD+0.15 GLY+0.15 MGLY : ARR2( 2.80e-11 , -175.0, TEMP ) ;
85 {084:061} UDD+HO=0.88 ALD+0.12 KET+HO2 : 2.70e-10 ;
86 {085:062} OP1+HO=0.65 MO2+0.35 HCHO+0.35 HO : ARR2( 2.93e-12 , -190.0, TEMP ) ;
87 {086:063} OP2+HO=0.44 HC3P+0.08 ALD+0.41 KET+0.49 HO+0.07 XO2 : ARR2( 3.40e-12 , -190.0, TEMP ) ;
88 {087:064} PAA+HO=0.35 HCHO+0.65 ACO3+0.35 HO2+0.35 XO2 : ARR2( 2.93e-12 , -190.0, TEMP ) ;
89 {088:065} PAN+HO=HCHO+XO2+H2O+NO3 : 4.00e-14 ;
90 {089:066} TPAN+HO=0.60 HKET+0.40 HCHO+0.40 HO2+XO2+0.40 PAN+0.60 NO3 : ARR2( 3.25e-13 , -500.0, TEMP ) ;
91 {090:067} ONIT+HO=HC3P+NO2+H2O : ARR2( 5.31e-12 , 260.0 , TEMP) ;
92 {091:068} HCHO+NO3=HO2+HNO3+CO : ARR2( 3.40e-13 , 1900.0, TEMP ) ;
93 {092:069} ALD+NO3=ACO3+HNO3 : ARR2( 1.40e-12 , 1900.0, TEMP ) ;
94 {093:070} GLY+NO3=HNO3+HO2+2.0 CO : ARR2( 2.90e-12 , 1900.0, TEMP ) ;
95 {094:071} MGLY+NO3=HNO3+ACO3+CO : ARR2( 1.40e-12 , 1900.0, TEMP ) ;
96 {095:072} MACR+NO3=0.20 TCO3+0.20 HNO3+0.80 OLNN+0.80 CO : ARR2(8.27E-15, 150.0, TEMP) ;
97 {096:073} DCB+NO3=0.5 TCO3+0.5 HO2+0.5 XO2+0.25 GLY+0.25 ALD+0.03 KET+0.25 MGLY+0.5 HNO3+0.5 NO2 : ARR2( 2.87e-13 , 1000.0, TEMP ) ;
98 {097:074} CSL+NO3=HNO3+PHO : 2.20e-11 ;
99 {098:075} ETE+NO3=0.80 OLNN+0.20 OLND : (THERMAL_T2( 4.88e-18 , 2282.0,TEMP )) ;
100 {099:076} OLT+NO3=0.43 OLNN+0.57 OLND : ARR2( 1.79e-13 , 450.0, TEMP ) ;
101 {100:077} OLI+NO3=0.11 OLNN+0.89 OLND : ARR2( 8.64e-13 , -450.0, TEMP ) ;
102 {101:078} DIEN+NO3=0.90 OLNN+0.10 OLND+0.90 MACR : 1.00e-13 ;
103 {102:079} ISO+NO3=0.90 OLNN+0.10 OLND+0.90 MACR : ARR2(4.0E-12, 446.0, TEMP) ;
104 {103:080} API+NO3=0.10 OLNN+0.90 OLND : ARR2( 1.19e-12 , -490.0, TEMP ) ;
105 {104:081} LIM+NO3=0.13 OLNN+0.87 OLND : 1.22e-11 ;
106 {105:082} TPAN+NO3=0.60 ONIT+0.60 NO3+0.40 PAN+0.40 HCHO+0.40 NO2+XO2 : ARR2( 2.20e-14 , 500.0, TEMP ) ;
107 {106:083} ETE+O3=HCHO+0.43 CO+0.37 ORA1+0.26 HO2+0.12 HO{+0.13 H2} : ARR2( 9.14e-15 , 2580.0, TEMP ) ;
108 {107:084} OLT+O3=0.64 HCHO+0.44 ALD+0.37 CO+0.14 ORA1+0.10 ORA2+0.25 HO2+0.40 HO+0.03 KET+0.03 KETP+0.06 CH4 +0.006 H2O2+0.03 ETH+0.19 MO2+0.10 ETHP{+0.05 H2} : ARR2( 4.33e-15, 1800.0, TEMP ) ;
109 {108:085} OLI+O3=0.02 HCHO+0.99 ALD+0.16 KET+0.30 CO+0.011 H2O2+0.14 ORA2+0.07 CH4+0.22 HO2+0.63 HO+0.23 MO2+0.12 KETP+0.06 ETH+0.18 ETHP : ARR2( 4.40e-15 , 845.0, TEMP ) ;
110 {109:086} DIEN+O3=0.90 HCHO+0.39 MACR+0.36 CO+0.15 ORA1+0.09 O3P+0.30 HO2+0.35 OLT+0.28 HO+0.15 ACO3+0.03 MO2+0.02 KETP+0.13 XO2+0.001 H2O2{+0.05 H2} : ARR2( 1.34e-14 , 2283.0, TEMP ) ;
111 {110:087} ISO+O3=0.9 HCHO+0.39 MACR+0.36 CO +0.15 ORA1+0.09 O3P+0.30 HO2 +0.35 OLT+0.28 HO +0.15 ACO3+0.03 MO2+0.02 KETP+0.13 XO2 +0.001 H2O2{+0.05 H2} : ARR2(7.86E-15, 1913.0, TEMP) ;
112 {111:088} API+O3=0.65 ALD+0.53 KET+0.14 CO+0.20 ETHP+0.42 KETP+0.85 HO+0.10 HO2+0.02 H2O2 : ARR2( 1.01e-15 , 732.0, TEMP ) ;
113 {112:089} LIM+O3=0.04 HCHO+0.46 OLT+0.14 CO+0.16 ETHP+0.42 KETP+0.85 HO+0.10 HO2+0.02 H2O2+0.79 MACR+0.01 ORA1+0.07 ORA2 : 2.00e-16 ;
114 {113:090} MACR+O3=0.40 HCHO+0.60 MGLY+0.13 ORA2+0.54 CO+0.22 ORA1+0.29 HO2+0.07 HO+0.13 OP2+0.13 ACO3 {+0.08 H2} : ARR2(1.36E-15, 2112.0, TEMP) ;
115 {114:091} DCB+O3=0.21 HO+0.29 HO2+0.66 CO+0.50 GLY+0.28 ACO3+0.16 ALD+0.62 MGLY+0.11 PAA+0.11 ORA1+0.21 ORA2 : 2.00e-18 ;
116 {115:092} TPAN+O3=0.70 HCHO+0.30 PAN+0.70 NO2+0.13 CO+0.11 ORA1+0.08 HO2+0.036 HO+0.70 ACO3{+0.04 H2} : ARR2( 2.46e-15 , 1700.0, TEMP ) ;
117 {116:093} PHO+NO2=0.10 CSL+ONIT : 2.00e-11 ;
118 {117:094} PHO+HO2=CSL : 1.00e-11 ;
119 {118:095} ADDT+NO2=CSL+HONO : 3.60e-11 ;
120 {119:096} ADDT+M {O2}=0.98 TOLP+0.02 CSL+0.02 HO2 : (.20946e0*ARR2( 1.66e-17 , -1044.0, TEMP )) ;
121 {120:097} ADDT+O3=CSL+HO : 5.00e-11 ;
122 {121:098} ADDX+NO2=CSL+HONO : 3.60e-11 ;
123 {122:099} ADDX+M{O2}=0.98 XYLP+0.02 CSL+0.02 HO2 : (.20946e0*ARR2( 1.66e-17 , -1044.0, TEMP )) ;
124 {123:100} ADDX+O3=CSL+HO : 1.00e-11 ;
125 {124:101} ADDC+NO2=CSL+HONO : 3.60e-11 ;
126 {125:102} ADDC+M{O2}=0.98 CSLP+0.02 CSL+0.02 HO2 : (.20946e0*ARR2( 1.66e-17 , -1044.0, TEMP )) ;
127 {126:103} ADDC+O3=CSL+HO : 5.00e-11 ;
128 {127:104} ACO3+NO2=PAN : TROE( 9.70e-29 , 5.6 , 9.30e-12 , 1.5 , TEMP, C_M) ;
129 {128:105} PAN=ACO3+NO2 : TROEE(1.16e28,13954.0, 9.70e-29 , 5.6 , 9.30e-12 , 1.5 , TEMP, C_M) ;
130 {129:106} TCO3+NO2=TPAN : TROE( 9.70e-29 , 5.6 , 9.30e-12 , 1.5 , TEMP, C_M) ;
131 {130:107} TPAN=TCO3+NO2 : TROEE(1.16e28,13954.0, 9.70e-29 , 5.6 , 9.30e-12 , 1.5 , TEMP, C_M ) ;
132 {131:108} MO2+NO=HCHO+HO2+NO2 : ARR2( 4.20e-12 , -180.0, TEMP ) ;
133 {132:109} ETHP+NO=ALD+HO2+NO2 : 8.70e-12 ;
134 {133:110} HC3P+NO=0.047 HCHO+0.233 ALD+0.623 KET+0.063 GLY+0.742 HO2+0.15 MO2+0.048 ETHP+0.048 XO2+0.059 ONIT+0.941 NO2 : 4.00e-12 ;
135 {134:111} HC5P+NO=0.021 HCHO+0.211 ALD+0.722 KET+0.599 HO2+0.031 MO2+0.245 ETHP+0.334 XO2+0.124 ONIT+0.876 NO2 : 4.00e-12 ;
136 {135:112} HC8P+NO=0.15 ALD+0.642 KET+0.133 ETHP+0.261 ONIT+0.739 NO2+0.606 HO2+0.416 XO2 : 4.00e-12 ;
137 {136:113} ETEP+NO=1.6 HCHO+HO2+NO2+0.2 ALD : 9.00e-12 ;
138 {137:114} OLTP+NO=0.94 ALD+HCHO+HO2+NO2+0.06 KET : 4.00e-12 ;
139 {138:115} OLIP+NO=HO2+1.71 ALD+0.29 KET+NO2 : 4.00e-12 ;
140 {139:116} ISOP+NO=0.446 MACR+0.354 OLT +0.847 HO2+0.606 HCHO+0.153 ONIT+0.847 NO2 : 4.0E-12 ;
141 {140:117} APIP+NO=0.80 HO2+0.80 ALD+0.80 KET+0.20 ONIT+0.80 NO2 : 4.00e-12 ;
142 {141:118} LIMP+NO=0.65 HO2+0.40 MACR+0.25 OLI+0.25 HCHO+0.35 ONIT+0.65 NO2 : 4.00e-12 ;
143 {142:119} TOLP+NO=0.95 NO2+0.95 HO2+0.65 MGLY+1.20 GLY+0.50 DCB+0.05 ONIT : 4.00e-12 ;
144 {143:120} XYLP+NO=0.95 NO2+0.95 HO2+0.60 MGLY+0.35 GLY+0.95 DCB+0.05 ONIT : 4.00e-12 ;
145 {144:121} CSLP+NO=GLY+MGLY+HO2+NO2 : 4.00e-12 ;
146 {145:122} ACO3+NO=MO2+NO2 : 2.00e-11 ;
147 {146:123} TCO3+NO=ACO3+HCHO+NO2 : 2.00e-11 ;
148 {147:124} KETP+NO=0.54 MGLY+0.46 ALD+0.23 ACO3+0.77 HO2+0.16 XO2+NO2 : 4.00e-12 ;
149 {148:125} OLNN+NO=HO2+ONIT+NO2 : 4.00e-12 ;
150 {149:126} OLND+NO=0.287 HCHO+1.24 ALD+0.464 KET+2.0 NO2 : 4.00e-12 ;
151 {150:127} MO2+HO2=OP1 : ARR2( 3.80e-13 , -800.0, TEMP ) ;
152 {151:128} ETHP+HO2=OP2 : ARR2( 7.50e-13 , -700.0, TEMP ) ;
153 {152:129} HC3P+HO2=OP2 : ARR2( 1.66e-13 , -1300.0, TEMP ) ;
154 {153:130} HC5P+HO2=OP2 : ARR2( 1.66e-13 , -1300.0, TEMP ) ;
155 {154:131} HC8P+HO2=OP2 : ARR2( 1.66e-13 , -1300.0, TEMP ) ;
156 {155:132} ETEP+HO2=OP2 : ARR2( 1.90e-13 , -1300.0, TEMP ) ;
157 {156:133} OLTP+HO2=OP2 : ARR2( 1.66e-13 , -1300.0, TEMP ) ;
158 {157:134} OLIP+HO2=OP2 : ARR2( 1.66e-13 , -1300.0, TEMP ) ;
159 {158:135} ISOP+HO2=OP2 : ARR2( 1.28E-13 , -1300.0, TEMP) ;
160 {159:136} APIP+HO2=OP2 : 1.50e-11 ;
161 {160:137} LIMP+HO2=OP2 : 1.50e-11 ;
162 {161:138} TOLP+HO2=OP2 : ARR2( 3.75e-13 , -980.0, TEMP ) ;
163 {162:139} XYLP+HO2=OP2 : ARR2( 3.75e-13 , -980.0, TEMP) ;
164 {163:140} CSLP+HO2=OP2 : ARR2( 3.75e-13 , -980.0, TEMP ) ;
165 {164:141} ACO3+HO2=PAA : ARR2( 1.15e-12 , -550.0, TEMP ) ;
166 {165:142} ACO3+HO2=ORA2+O3 : ARR2( 3.86e-16 , -2640.0, TEMP ) ;
167 {166:143} TCO3+HO2=OP2 : ARR2( 1.15e-12 , -550.0, TEMP ) ;
168 {167:144} TCO3+HO2=ORA2+O3 : ARR2( 3.86e-16 , -2640.0, TEMP ) ;
169 {168:145} KETP+HO2=OP2 : ARR2( 1.15e-13 , -1300.0, TEMP ) ;
170 {169:146} OLNN+HO2=ONIT : ARR2( 1.66e-13 , -1300.0, TEMP ) ;
171 {170:147} OLND+HO2=ONIT : ARR2( 1.66e-13 , -1300.0, TEMP ) ;
172 {171:148} MO2+MO2=1.33 HCHO+0.66 HO2 : ARR2( 9.10e-14 , -416.0, TEMP ) ;
173 {172:149} ETHP+MO2=0.75 HCHO+HO2+0.75 ALD : ARR2( 1.18e-13 , -158.0, TEMP ) ;
174 {173:150} HC3P+MO2=0.81 HCHO+0.992 HO2+0.58 ALD+0.018 KET+0.007 MO2+0.005 MGLY+0.085 XO2+0.119 GLY : ARR2( 9.46e-14 , -431.0 , TEMP) ;
175 {174:151} HC5P+MO2=0.829 HCHO+0.946 HO2+0.523 ALD+0.24 KET+0.014 ETHP+0.049 MO2+0.245 XO2 : ARR2( 1.00e-13 , -467.0, TEMP ) ;
176 {175:152} HC8P+MO2=0.753 HCHO+0.993 HO2+0.411 ALD+0.419 KET+0.322 XO2+0.013 ETHP : ARR2( 4.34e-14 , -633.0, TEMP ) ;
177 {176:153} ETEP+MO2=1.55 HCHO+HO2+0.35 ALD : ARR2( 1.71e-13 , -708.0, TEMP ) ;
178 {177:154} OLTP+MO2=1.25 HCHO+HO2+0.669 ALD+0.081 KET : ARR2( 1.46e-13 , -708.0, TEMP ) ;
179 {178:155} OLIP+MO2=0.755 HCHO+HO2+0.932 ALD+0.313 KET : ARR2( 9.18e-14 , -708.0, TEMP ) ;
180 {179:156} ISOP+MO2=0.550 MACR+0.370 OLT+HO2+0.08 OLI+1.09 HCHO : ARR2( 1.36e-13 , -708.0, TEMP ) ;
181 {180:157} APIP+MO2=HCHO+ALD+KET+2.0 HO2 : ARR2( 3.56e-14 , -708.0, TEMP ) ;
182 {181:158} LIMP+MO2=1.4 HCHO+0.60 MACR+0.40 OLI+2.0 HO2 : ARR2( 3.56e-14 , -708.0, TEMP ) ;
183 {182:159} TOLP+MO2=HCHO+HO2+0.35 MGLY+0.65 GLY+DCB : ARR2( 3.56e-14 , -708.0, TEMP ) ;
184 {183:160} XYLP+MO2=HCHO+HO2+0.63 MGLY+0.37 GLY+DCB : ARR2( 3.56e-14 , -708.0, TEMP ) ;
185 {184:161} CSLP+MO2=GLY+MGLY+HCHO+2.0 HO2 : ARR2( 3.56e-14 , -708.0, TEMP ) ;
186 {185:162} ACO3+MO2=HCHO+HO2+MO2 : ARR2( 3.21e-11 , 440.0, TEMP ) ;
187 {186:163} ACO3+MO2=HCHO+ORA2 : ARR2( 2.68e-16 , -2510.0, TEMP ) ;
188 {187:164} TCO3+MO2=2.0 HCHO+HO2+ACO3 : ARR2( 3.21e-11 , 440.0, TEMP ) ;
189 {188:165} TCO3+MO2=HCHO+ORA2 : ARR2( 2.68e-16 , -2510.0, TEMP ) ;
190 {189:166} KETP+MO2=0.75 HCHO+0.88 HO2+0.40 MGLY+0.30 ALD+0.30 HKET+0.12 ACO3+0.08 XO2 : ARR2( 6.91e-13 , -508.0, TEMP ) ;
191 {190:167} OLNN+MO2=0.75 HCHO+HO2+ONIT : ARR2( 1.60e-13 , -708.0, TEMP ) ;
192 {191:168} OLND+MO2=0.96 HCHO+0.5 HO2+0.64 ALD+0.149 KET+0.5 NO2+0.5 ONIT : ARR2( 9.68e-14 , -708.0, TEMP ) ;
193 {192:169} ETHP+ACO3=ALD+0.5 HO2+0.5 MO2+0.5 ORA2 : ARR2( 1.03e-12 , -211.0, TEMP ) ;
194 {193:170} HC3P+ACO3=0.724 ALD+0.127 KET+0.488 HO2+0.508 MO2+0.006 ETHP+0.071 XO2+0.091 HCHO+0.10 GLY+0.499 ORA2+0.004 MGLY : ARR2( 6.90e-13 , -460.0, TEMP ) ;
195 {194:171} HC5P+ACO3=0.677 ALD+0.33 KET+0.438 HO2+0.554 MO2+0.495 ORA2+0.018 ETHP+0.237 XO2+0.076 HCHO : ARR2( 5.59e-13 , -522.0, TEMP ) ;
196 {195:172} HC8P+ACO3=0.497 ALD+0.581 KET+0.489 HO2+0.507 MO2+0.495 ORA2+0.015 ETHP+0.318 XO2 : ARR2( 2.47e-13 , -683.0, TEMP ) ;
197 {196:173} ETEP+ACO3=0.8 HCHO+0.6 ALD+0.5 HO2+0.5 MO2+0.5 ORA2 : ARR2( 9.48e-13 , -765.0, TEMP ) ;
198 {197:174} OLTP+ACO3=0.859 ALD+0.501 HCHO+0.501 HO2+0.501 MO2+0.499 ORA2+0.141 KET : ARR2( 8.11e-13 , -765.0, TEMP ) ;
199 {198:175} OLIP+ACO3=0.941 ALD+0.569 KET+0.51 HO2+0.51 MO2+0.49 ORA2 : ARR2( 5.09e-13 , -765.0, TEMP ) ;
200 {199:176} ISOP+ACO3=0.771 MACR+0.229 OLT+0.506 HO2+0.494 ORA2+0.340 HCHO+0.506 MO2 : ARR2( 7.60e-13 , -765.0, TEMP ) ;
201 {200:177} APIP+ACO3=ALD+KET+HO2+MO2 : ARR2( 7.40e-13 , -765.0, TEMP ) ;
202 {201:178} LIMP+ACO3=0.60 MACR+0.40 OLI+0.40 HCHO+HO2+MO2 : ARR2( 7.40e-13 , -765.0, TEMP ) ;
203 {202:179} TOLP+ACO3=MO2+HO2+0.35 MGLY+0.65 GLY+DCB : ARR2( 7.40e-13 , -765.0, TEMP ) ;
204 {203:180} XYLP+ACO3=MO2+HO2+0.63 MGLY+0.37 GLY+DCB : ARR2( 7.40e-13 , -765.0, TEMP ) ;
205 {204:181} CSLP+ACO3=GLY+MGLY+MO2+HO2 : ARR2( 7.40e-13 , -765.0, TEMP ) ;
206 {205:182} ACO3+ACO3=2.0 MO2 : ARR2( 2.80e-12 , -530.0, TEMP ) ;
207 {206:183} TCO3+ACO3=MO2+ACO3+HCHO : ARR2( 2.80e-12 , -530.0, TEMP ) ;
208 {207:184} KETP+ACO3=0.54 MGLY+0.35 ALD+0.11 KET+0.12 ACO3+0.38 HO2+0.08 XO2+0.5 MO2+0.5 ORA2 : ARR2( 7.51e-13 , -565.0, TEMP ) ;
209 {208:185} OLNN+ACO3=ONIT+0.5 ORA2+0.5 MO2+0.5 HO2 : ARR2( 8.85e-13 , -765.0, TEMP ) ;
210 {209:186} OLND+ACO3=0.207 HCHO+0.65 ALD+0.167 KET+0.484 ORA2+0.484 ONIT+0.516 NO2+0.516 MO2 : ARR2( 5.37e-13 , -765.0, TEMP ) ;
211 {210:187} OLNN+OLNN=2.0 ONIT+HO2 : ARR2( 7.00e-14 , -1000.0 , TEMP) ;
212 {211:188} OLNN+OLND=0.202 HCHO+0.64 ALD+0.149 KET+0.50 HO2+1.50 ONIT+0.50 NO2 : ARR2( 4.25e-14 , -1000.0, TEMP ) ;
213 {212:189} OLND+OLND=0.504 HCHO+1.21 ALD+0.285 KET+ONIT+NO2 : ARR2( 2.96e-14 , -1000.0, TEMP ) ;
214 {213:190} MO2+NO3=HCHO+HO2+NO2 : 1.20e-12 ;
215 {214:191} ETHP+NO3=ALD+HO2+NO2 : 1.20e-12 ;
216 {215:192} HC3P+NO3=0.048 HCHO+0.243 ALD+0.67 KET+0.063 GLY+0.792 HO2+0.155 MO2+0.053 ETHP+0.051 XO2+NO2 : 1.20e-12 ;
217 {216:193} HC5P+NO3=0.021 HCHO+0.239 ALD+0.828 KET+0.699 HO2+0.04 MO2+0.262 ETHP+0.391 XO2+NO2 : 1.20e-12 ;
218 {217:194} HC8P+NO3=0.187 ALD+0.88 KET+0.845 HO2+0.155 ETHP+0.587 XO2+NO2 : 1.20e-12 ;
219 {218:195} ETEP+NO3=1.6 HCHO+0.2 ALD+HO2+NO2 : 1.20e-12 ;
220 {219:196} OLTP+NO3=HCHO+0.94 ALD+0.06 KET+HO2+NO2 : 1.20e-12 ;
221 {220:197} OLIP+NO3=1.71 ALD+0.29 KET+HO2+NO2 : 1.20e-12 ;
222 {221:198} ISOP+NO3=0.60 MACR+0.40 OLT +0.686 HCHO+HO2+NO2 : 1.20E-12 ;
223 {222:199} APIP+NO3=ALD+KET+HO2+NO2 : 1.20e-12 ;
224 {223:200} LIMP+NO3=0.60 MACR+0.40 OLI+0.40 HCHO+HO2+NO2 : 1.20e-12 ;
225 {224:201} TOLP+NO3=0.70 MGLY+1.30 GLY+0.50 DCB+HO2+NO2 : 1.20e-12 ;
226 {225:202} XYLP+NO3=1.26 MGLY+0.74 GLY+DCB+HO2+NO2 : 1.20e-12 ;
227 {226:203} CSLP+NO3=GLY+MGLY+HO2+NO2 : 1.20e-12;
228 {227:204} ACO3+NO3=MO2+NO2 : 4.00e-12;
229 {228:205} TCO3+NO3=HCHO+ACO3+NO2 : 4.00e-12;
230 {229:206} KETP+NO3=0.54 MGLY+0.46 ALD+0.77 HO2+0.23 ACO3+0.16 XO2+NO2 : 1.20e-12 ;
231 {230:207} OLNN+NO3=ONIT+HO2+NO2 : 1.20e-12 ;
232 {231:208} OLND+NO3=0.28 HCHO+1.24 ALD+0.469 KET+2.0 NO2 : 1.20e-12 ;
233 {232:209} XO2+HO2=OP2 : ARR2( 1.66e-13 , -1300.0, TEMP ) ;
234 {233:210} XO2+MO2=HCHO+HO2 : ARR2( 5.99e-15 , -1510.0, TEMP ) ;
235 {234:211} XO2+ACO3=MO2 : ARR2( 3.40e-14 , -1560.0, TEMP ) ;
236 {235:212} XO2+XO2=M{O2} : ARR2( 7.13e-17 , -2950.0, TEMP ) ;
237 {236:213} XO2+NO=NO2 : 4.00e-12 ;
238 {237:214} XO2+NO3=NO2 : 1.20e-12 ;