| blob | 7cf3f4a5874f79d2c8016896e3aa823d698c9958 |
1 #Equations
3 {1} NO2 + hv = NO + O3P : 1.0*SUN;
4 {2} O3P + O2 + AIR = O3 : ARR(5.68e-34,0.0,-2.80);
5 {3} O3P + O3 = 2O2 : ARR(8.00e-12,2060.0,0.0);
6 {4} O3P + NO + AIR = NO2 : ARR(1.00e-31,0.0,-1.60);
7 {5} O3P + NO2 = NO : ARR(6.50e-12,-120.0,0.0);
8 {6} O3P + NO2 = NO3 : FALL(9.00e-32,0.0,-2.00,2.20e-11,0.0,0.0,0.80);
9 {7} O3 + NO = NO2 : ARR(1.80e-12,1370.0,0.0);
10 {8} O3 + NO2 = NO3 : ARR(1.40e-13,2470.0,0.0);
11 {9} NO + NO3 = 2NO2 : ARR(1.80e-11,-110.0,0.0);
12 {10} NO + NO + O2 = 2NO2 : ARR(3.30e-39,-530.0,0.0);
13 {11} NO2 + NO3 = N2O5 : FALL(2.80e-30,0.0,-3.50,2.00e-12,0.0,0.20,0.45);
14 {12} N2O5 = NO2 + NO3 : FALL(1.e-3,11000.0,-3.5,9.7e14,11080.0,0.1,0.45);
15 {13} N2O5 + H2O = 2HNO3 : 2.60e-22;
16 {14} NO2 + NO3 = NO + NO2 : ARR(4.50e-14,1260.0,0.0);
17 {15} NO3 + hv = NO : 1.0*SUN;
18 {16} NO3 + hv = NO2 + O3P : 1.0*SUN;
19 {17} O3 + hv = O3P : 1.0*SUN;
20 {18} O3 + hv = O1D : 1.0*SUN;
21 {19} O1D + H2O = 2OH : 2.20e-10;
22 {20} O1D + AIR = O3P : ARR(2.09e-11,-95.0,0.0);
23 {21} OH + NO = HONO : FALL(7.00e-31,0.0,-2.60,3.60e-11,0.0,-0.10,0.60);
24 {22} HONO + hv = OH + NO : 1.0*SUN;
25 {23} HONO + hv = HO2 + NO2 : 1.0*SUN;
26 {24} OH + HONO = NO2 : ARR(2.70e-12,-260.0,0.0);
27 {25} OH + NO2 = HNO3 : FALL(2.43e-30, 0.0,-3.10,1.67e-11,0.0,-2.10,0.60);
28 {26} OH + NO3 = HO2 + NO2 : 2.00e-11;
29 {27} OH + HNO3 = NO3 : EP2(7.20e-15,-785.0,4.10e-16,-1440.0,1.90e-33,-725.0);
30 {28} HNO3 + hv = OH + NO2 : 1.0*SUN;
31 {29} OH + CO = HO2 : EP3(1.30e-13,0.0,3.19e-33,0.0);
32 {30} OH + O3 = HO2 : ARR(1.90e-12,1000.0,0.0);
33 {31} HO2 + NO = OH + NO2 : ARR(3.40e-12,-270.0,0.0);
34 {32} HO2 + NO2 = HNO4 : FALL(1.80e-31,0.0,-3.20,4.70e-12,0.0,0.0,0.60);
35 {33} HNO4 = HO2 + NO2 : FALL(4.10e-05,10650.0,0.0,5.7e+15,11170.0,0.0,0.5);
36 {34} HNO4 + hv = 0.61HO2 + 0.61NO2 + 0.39OH +
37 0.39NO3 : 1.0*SUN;
38 {35} HNO4 + OH = NO2 : ARR(1.50e-12,-360.0,0.0);
39 {36} HO2 + O3 = OH : ARR(1.40e-14,600.0,0.0);
40 {37} HO2 + HO2 = H2O2 : EP3(2.20e-13,-600.0,1.85e-33,-980.0);
41 {38} HO2 + HO2 + H2O = H2O2 : EP3(3.08e-34,-2800.0,2.59e-54,-3180.0);
42 {39} NO3 + HO2 = 0.8OH + 0.8NO2 + 0.2HNO3 : 4.00e-12;
43 {40} NO3 + NO3 = 2NO2 : ARR(8.50e-13,2450.0,0.0);
44 {41} H2O2 + hv = 2OH : 1.0*SUN;
45 {42} H2O2 + OH = HO2 : ARR(2.90e-12,160.0,0.0);
46 {43} OH + HO2 = H2O + O2 : ARR(4.80e-11,-250.0,0.0);
47 {44} OH + SO2 = HO2 + H2SO4 : FALL(4.00e-31,0.0,-3.30,2.00e-12,0.0,0.0,0.45);
48 {45} OH + H2 = HO2 : ARR(7.70e-12,2100.0,0.0);
49 {46} C_O2 + NO = NO2 + HCHO + HO2 : ARR(2.80e-12,-285.0,0.0);
50 {47} C_O2 + HO2 = COOH : ARR(3.80e-13,-780.0,0.0);
51 {48} C_O2 + NO3 = HCHO + HO2 + NO2 : 1.30e-12;
52 {49} C_O2 + C_O2 = MEOH + HCHO : ARR(2.45e-14,-710.0,0.0);
53 {50} C_O2 + C_O2 = 2HCHO + 2HO2 : ARR(5.90e-13,509.0,0.0);
54 {51} RO2_R + NO = NO2 + HO2 : ARR(2.70e-12,-360.0,0.0);
55 {52} RO2_R + HO2 = ROOH : ARR(1.90e-13,-1300.0,0.0);
56 {53} RO2_R + NO3 = NO2 + HO2 : 2.30e-12;
57 {54} RO2_R + C_O2 = HO2 + 0.75HCHO +
58 0.25MEOH : 2.00e-13;
59 {55} RO2_R + RO2_R = HO2 : 3.50e-14;
60 {56} R2O2 + NO = NO2 : ARR(2.70e-12,-360.0,0.0); {1.0*RCONST(51);}
61 {57} R2O2 + HO2 = HO2 : ARR(1.90e-13,-1300.0,0.0); {1.0*RCONST(52);}
62 {58} R2O2 + NO3 = NO2 : 2.30e-12; {1.0*RCONST(53);}
63 {59} R2O2 + C_O2 = C_O2 : 2.00e-13; {1.0*RCONST(54);}
64 {60} R2O2 + RO2_R = RO2_R : 3.50e-14; {1.0*RCONST(55);}
65 {61} R2O2 + R2O2 = 2R2O2 : 0.0;
66 {62} RO2_N + NO = RNO3 : ARR(2.70e-12,-360.0,0.0); {1.0*RCONST(51);}
67 {63} RO2_N + HO2 = ROOH : ARR(1.90e-13,-1300.0,0.0); {1.0*RCONST(52);}
68 {64} RO2_N + C_O2 = HO2 + 0.25MEOH +
69 0.5MEK + 0.5PROD2 + 0.75HCHO : 2.00e-13; {1.0*RCONST(54);}
70 {65} RO2_N + NO3 = NO2 + HO2 + MEK : 2.30e-12; {1.0*RCONST(53);}
71 {66} RO2_N + RO2_R = HO2 + 0.5MEK +
72 0.5PROD2 : 3.50e-14; {1.0*RCONST(55);}
73 {67} RO2_N + R2O2 = RO2_N : 3.50e-14; {1.0*RCONST(55);}
74 {68} RO2_N + RO2_N = MEK + HO2 + PROD2 : 3.50e-14; {1.0*RCONST(55);}
75 {69} CCO_O2 + NO2 = PAN : FALL(2.70e-28,0.0,-7.10,1.20e-11,0.0,-0.90,0.30);
76 {70} PAN = CCO_O2 + NO2 : FALL(4.90e-3,12100.0,0.0,4.0e+16,13600.0,0.,0.3);
77 {71} CCO_O2 + NO = C_O2 + NO2 : ARR(7.80e-12,-300.0,0.0);
78 {72} CCO_O2 + HO2 = 0.75CCO_OOH +
79 0.25CCO_OH + 0.25O3 : ARR(4.30e-13,-1040.0,0.0);
80 {73} CCO_O2 + NO3 = C_O2 + NO2 : 4.00e-12;
81 {74} CCO_O2 + C_O2 = CCO_OH + HCHO : ARR(1.80e-12,-500.0,0.0);
82 {75} CCO_O2 + RO2_R = CCO_OH : 7.50e-12;
83 {76} CCO_O2 + R2O2 = CCO_O2 : 7.50e-12;
84 {77} CCO_O2 + RO2_N = CCO_OH + PROD2 : 7.50e-12;
85 {78} CCO_O2 + CCO_O2 = 2C_O2 : ARR(2.90e-12,-500.0,0.0);
86 {79} RCO_O2 + NO2 = PAN2 : ARR(1.20e-11,0.0,-0.90);
87 {80} PAN2 = RCO_O2 + NO2 : ARR(2.00e+15,12800.0,0.0);
88 {81} RCO_O2 + NO = NO2 + CCHO + RO2_R : ARR(1.25e-11,-240.0,0.0);
89 {82} RCO_O2 + HO2 = 0.75RCO_OOH +
90 0.25RCO_OH + 0.25O3 : ARR(4.30e-13,-1040.0,0.0); {1.0*RCONST(72);}
91 {83} RCO_O2 + NO3 = NO2 + CCHO + RO2_R : 4.00e-12; {1.0*RCONST(73);}
92 {84} RCO_O2 + C_O2 = RCO_OH + HCHO : ARR(1.80e-12,-500.0,0.0); {1.0*RCONST(74);}
93 {85} RCO_O2 + RO2_R = RCO_OH : 7.50e-12; {1.0*RCONST(75);}
94 {86} RCO_O2 + R2O2 = RCO_O2 : 7.50e-12; {1.0*RCONST(75);}
95 {87} RCO_O2 + RO2_N = RCO_OH + PROD2 : 7.50e-12; {1.0*RCONST(75);}
96 {88} RCO_O2 + CCO_O2 = C_O2 + CCHO + RO2_R : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);}
97 {89} RCO_O2 + RCO_O2 = 2CCHO + 2RO2_R : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);}
98 {90} BZCO_O2 + NO2 = PBZN : 1.37e-11;
99 {91} PBZN = BZCO_O2 + NO2 : ARR(7.90e+16,14000.0,0.0);
100 {92} BZCO_O2 + NO = NO2 + BZ_O + R2O2 : ARR(1.25e-11,-240.0,0.0); {1.0*RCONST(81);}
101 {93} BZCO_O2 + HO2 = 0.75RCO_OOH +
102 0.25RCO_OH + 0.25O3 : ARR(4.30e-13,-1040.0,0.0); {1.0*RCONST(72);}
103 {94} BZCO_O2 + NO3 = NO2 + BZ_O + R2O2 : 4.00e-12; {1.0*RCONST(73);}
104 {95} BZCO_O2 + C_O2 = RCO_OH + HCHO : ARR(1.80e-12,-500.0,0.0); {1.0*RCONST(74);}
105 {96} BZCO_O2 + RO2_R = RCO_OH : 7.50e-12; {1.0*RCONST(75);}
106 {97} BZCO_O2 + R2O2 = BZCO_O2 : 7.50e-12; {1.0*RCONST(75);}
107 {98} BZCO_O2 + RO2_N = RCO_OH + PROD2 : 7.50e-12; {1.0*RCONST(75);}
108 {99} BZCO_O2 + CCO_O2 = C_O2 + BZ_O + R2O2 : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);}
109 {100} BZCO_O2 + RCO_O2 = CCHO + RO2_R +
110 BZ_O + R2O2 : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);}
111 {101} BZCO_O2 + BZCO_O2 = 2BZ_O + 2R2O2: ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);}
112 {102} MA_RCO3 + NO2 = MA_PAN : ARR(1.20e-11,0.0,-0.90); {1.0*RCONST(79);}
113 {103} MA_PAN = MA_RCO3 + NO2 : ARR(1.60e+16,13486.0,0.0);
114 {104} MA_RCO3 + NO = NO2 + HCHO + CCO_O2 : ARR(1.25e-11,-240.0,0.0); {1.0*RCONST(81);}
115 {105} MA_RCO3 + HO2 = 0.75RCO_OOH +
116 0.25RCO_OH + 0.25O3 : ARR(4.30e-13,-1040.0,0.0); {1.0*RCONST(72);}
117 {106} MA_RCO3 + NO3 = NO2 + HCHO + CCO_O2 : 4.00e-12; {1.0*RCONST(73);}
118 {107} MA_RCO3 + C_O2 = RCO_OH + HCHO : ARR(1.80e-12,-500.0,0.0); {1.0*RCONST(74);}
119 {108} MA_RCO3 + RO2_R = RCO_OH : 7.50e-12; {1.0*RCONST(75);}
120 {109} MA_RCO3 + R2O2 = MA_RCO3 : 7.50e-12; {1.0*RCONST(75);}
121 {110} MA_RCO3 + RO2_N = 2RCO_OH : 7.50e-12; {1.0*RCONST(75);}
122 {111} MA_RCO3 + CCO_O2 = C_O2 + HCHO +
123 CCO_O2 : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);}
124 {112} MA_RCO3 + RCO_O2 = HCHO + CCO_O2 +
125 CCHO + RO2_R : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);}
126 {113} MA_RCO3 + BZCO_O2 = HCHO + CCO_O2 +
127 BZ_O + R2O2 : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);}
128 {114} MA_RCO3 + MA_RCO3 = 2HCHO + 2CCO_O2 : ARR(2.90e-12,-500.0,0.0); {1.0*RCONST(78);}
129 {115} TBU_O + NO2 = RNO3 : 2.40e-11;
130 {116} TBU_O = ACET + C_O2 : ARR(7.50e+14,8152.0,0.0);
131 {117} BZ_O + NO2 = NPHE : ARR(2.30e-11,-150.0,0.0);
132 {118} BZ_O + HO2 = PHEN : ARR(1.90e-13,-1300.0,0.0); {1.0*RCONST(52);}
133 {119} BZ_O = PHEN : 1.00e-03;
134 {120} BZNO2_O + NO2 = 2XN + 6XC: ARR(7.50e+14,8152.0,0.0); {1.0*RCONST(116);}
135 {121} BZNO2_O + HO2 = NPHE : ARR(2.30e-11,-150.0,0.0); {1.0*RCONST(117);}
136 {122} BZNO2_O = NPHE : ARR(1.90e-13,-1300.0,0.0); {1.0*RCONST(118);}
137 {123} HCHO + hv = 2HO2 + CO : 1.0*SUN;
138 {124} HCHO + hv = CO : 1.0*SUN;
139 {125} HCHO + OH = HO2 + CO : ARR(8.60e-12,-20.0,0.0);
140 {126} HCHO + HO2 = HOCOO : ARR(9.70e-15,-625.0,0.0);
141 {127} HOCOO = HO2 + HCHO : ARR(2.40e+12,7000.0,0.0);
142 {128} HOCOO + NO = HCOOH + NO2 + HO2 : ARR(2.80e-12,-285.0,0.0); {1.0*RCONST(46);}
143 {129} HCHO + NO3 = HNO3 + HO2 + CO : ARR(2.00e-12,2431.0,0.0);
144 {130} CCHO + OH = CCO_O2 : ARR(5.60e-12,-310.0,0.0);
145 {131} CCHO +hv = CO + HO2 + C_O2 : 1.0*SUN;
146 {132} CCHO + NO3 = HNO3 + CCO_O2 : ARR(1.40e-12,1860.0,0.0);
147 {133} RCHO + OH = 0.034RO2_R + 0.001RO2_N +
148 0.965RCO_O2 + 0.034CO+ 0.034CCHO : 2.00e-11;
149 {134} RCHO + hv = CCHO + RO2_R + CO + HO2 : 1.0*SUN;
150 {135} RCHO + NO3 = HNO3 + RCO_O2 : ARR(1.40e-12,1771.0,0.0);
151 {136} ACET + OH = HCHO + CCO_O2 + R2O2 : ARR(1.10e-12,520.0,0.0);
152 {137} ACET + hv = CCO_O2 + C_O2 : 1.0*SUN;
153 {138} MEK + OH = 0.37RO2_R + 0.042RO2_N +
154 0.616R2O2+ 0.492CCO_O2 +
155 0.096RCO_O2 + 0.115HCHO +
156 0.482CCHO + 0.37RCHO : ARR(1.30e-12,25.0,2.0);
157 {139} MEK + hv = CCO_O2 + CCHO + RO2_R : 1.50e-1*SUN;
158 {140} MEOH + OH = HCHO + HO2 : ARR(3.10e-12,360.0,2.0);
159 {141} ETOH + OH = 0.95HO2 + 0.05RO2_R +
160 0.081HCHO + 0.96CCHO : ARR(0.0,0.0,1.0);
161 {142} COOH + OH = 0.35HCHO + 0.35OH +
162 0.65C_O2 : ARR(2.90e-12,-190.0,0.0);
163 {143} COOH + hv = HCHO + HO2 + OH : 1.0*SUN;
164 {144} ROOH + OH = RCHO + 0.34RO2_R +
165 0.66OH : 1.10e-11;
166 {145} ROOH + hv = RCHO + HO2 + OH : 1.0*SUN;
167 {146} GLY + hv = 2CO+ 2HO2 : 1.0*SUN;
168 {147} GLY + hv = HCHO + CO : 6.00e-3*SUN;
169 {148} GLY + OH = 0.63HO2 + 1.26CO+
170 0.37RCO_O2 : 1.10e-11;
171 {149} GLY + NO3 = HNO3 + 0.63HO2 +
172 1.26CO+ 0.37RCO_O2 : ARR(2.80e-12,2376.0,0.0);
173 {150} MGLY + hv = HO2 + CO + CCO_O2 : 1.0*SUN;
174 {151} MGLY + OH = CO + CCO_O2 : 1.50e-11;
175 {152} MGLY + NO3 = HNO3 + CO + CCO_O2 : ARR(1.40e-12,1895.0,0.0);
176 {153} BACL + hv = 2CCO_O2 : 1.0*SUN;
177 {154} PHEN + OH = 0.24BZ_O + 0.76RO2_R +
178 0.23GLY : 2.63e-11;
179 {155} PHEN + NO3 = HNO3 + BZ_O : 3.78e-12;
180 {156} CRES + OH = 0.24BZ_O + 0.76RO2_R +
181 0.23MGLY : 4.20e-11;
182 {157} CRES + NO3 = HNO3 + BZ_O : 1.37e-11;
183 {158} NPHE + NO3 = HNO3 + BZNO2_O : 2.63e-11; {1.0*RCONST(154);}
184 {159} BALD + OH = BZCO_O2 : 1.29e-11;
185 {160} BALD + hv = 7XC: 5.00e-2*SUN;
186 {161} BALD + NO3 = HNO3 + BZCO_O2 : ARR(1.40e-12,1872.0,0.0);
187 {162} METHACRO + OH = 0.5RO2_R + 0.416CO+
188 0.084HCHO + 0.416MEK +
189 0.084MGLY + 0.5MA_RCO3 : ARR(1.86e-11,-176.0,0.0);
190 {163} METHACRO + O3 = 0.008HO2 + 0.1RO2_R +
191 0.208OH + 0.1RCO_O2 + 0.45CO+
192 0.2HCHO + 0.9MGLY + 0.333HCOOH : ARR(1.36e-15,2114.0,0.0);
193 {164} METHACRO + NO3 = 0.5HNO3 + 0.5RO2_R +
194 0.5CO+ 0.5MA_RCO3 : ARR(1.50e-12,1726.0,0.0);
195 {165} METHACRO + O3P = RCHO : 6.34e-12;
196 {166} METHACRO + hv = 0.34HO2 + 0.33RO2_R +
197 0.33OH + 0.67CCO_O2 + 0.67CO+
198 0.67HCHO + 0.33MA_RCO3 : 4.10e-3*SUN;
199 {167} MVK + OH = 0.3RO2_R + 0.025RO2_N +
200 0.675R2O2+ 0.675CCO_O2 +
201 0.3HCHO + 0.675RCHO + 0.3MGLY : ARR(4.14e-12,-453.0,0.0);
202 {168} MVK + O3 = 0.064HO2 + 0.05RO2_R +
203 0.164OH + 0.05RCO_O2 + 0.475CO+
204 0.1HCHO + 0.95MGLY + 0.351HCOOH : ARR(7.51e-16,1520.0,0.0);
205 {169} MVK + O3P = 0.45RCHO + 0.55MEK : 4.32e-12;
206 {170} MVK + hv = 0.3C_O2 + 0.7CO+ 0.7PROD2 +
207 0.3MA_RCO3 : 2.10e-3*SUN;
208 {171} ISOPROD + OH = 0.67RO2_R +
209 0.041RO2_N + 0.289MA_RCO3 +
210 0.336CO+ 0.055HCHO + 0.129CCHO +
211 0.013RCHO + 0.15MEK + 0.332PROD2 +
212 0.15GLY + 0.174MGLY : 6.19e-11;
213 {172} ISOPROD + O3 = 0.4HO2 + 0.048RO2_R +
214 0.048RCO_O2 + 0.285OH +
215 0.498CO+ 0.125HCHO + 0.047CCHO +
216 0.21MEK + 0.023GLY + 0.742MGLY +
217 0.1HCOOH + 0.372RCO_OH : 4.18e-18;
218 {173} ISOPROD + NO3 = 0.799RO2_R +
219 0.051RO2_N + 0.15MA_RCO3 + 0.572CO+
220 0.15HNO3 + 0.227HCHO + 0.218RCHO +
221 0.008MGLY + 0.572RNO3 : 1.00e-13;
222 {174} ISOPROD + hv = 1.233HO2 + 0.467CCO_O2 +
223 0.3RCO_O2 + 1.233CO+ 0.3HCHO +
224 0.467CCHO + 0.233MEK : 4.10e-3*SUN;
225 {175} PROD2 + OH = 0.379HO2 + 0.473RO2_R +
226 0.07RO2_N + 0.029CCO_O2 +
227 0.049RCO_O2 + 0.213HCHO +
228 0.084CCHO + 0.558RCHO +
229 0.115MEK + 0.329PROD2 : 1.50e-11;
230 {176} PROD2 + hv = 0.96RO2_R + 0.04RO2_N +
231 0.515R2O2+ 0.667CCO_O2 +
232 0.333RCO_O2 + 0.506HCHO +
233 0.246CCHO + 0.71RCHO : 2.00e-2*SUN;
234 {177} RNO3 + OH = 0.338NO2 + 0.113HO2 +
235 0.376RO2_R + 0.173RO2_N +
236 0.596R2O2+ 0.01HCHO +
237 0.439CCHO + 0.213RCHO +
238 0.006ACET + 0.177MEK +
239 0.048PROD2 + 0.31RNO3 : 7.80e-12;
240 {178} RNO3 + hv = NO2 + 0.341HO2 + 0.564RO2_R +
241 0.095RO2_N + 0.152R2O2+ 0.134HCHO +
242 0.431CCHO + 0.147RCHO + 0.02ACET +
243 0.243MEK + 0.435PROD2 : 1.0*SUN;
244 {179} DCB1 + OH = RCHO + RO2_R + CO : 5.00e-11;
245 {180} DCB1 + O3 = 1.5HO2 + 0.5OH +
246 1.5CO + GLY : 2.00e-18;
247 {181} DCB2 + OH = R2O2 + RCHO + CCO_O2 : 5.00e-11;
248 {182} DCB2 + hv = RO2_R + 0.5CCO_O2 + 0.5HO2 +
249 CO + R2O2 + 0.5GLY + 0.5MGLY : 3.65e-1*SUN;
250 {183} DCB3 + OH = R2O2 + RCHO + CCO_O2 : 5.00e-11;
251 {184} DCB3 + hv = RO2_R + 0.5CCO_O2 + 0.5HO2 +
252 CO + R2O2 + 0.5GLY + 0.5MGLY : 7.28*SUN;
253 {185} CH4 + OH = C_O2 : ARR(2.15e-12,1735.0,0.0);
254 {186} ETHENE + OH = RO2_R + 1.61HCHO +
255 0.195CCHO : ARR(1.96e-12,-438.0,0.0);
256 {187} ETHENE + O3 = 0.12OH + 0.12HO2 +
257 0.5CO+ HCHO + 0.37HCOOH : ARR(9.14e-15,2580.0,0.0);
258 {188} ETHENE + NO3 = RO2_R + RCHO : ARR(4.39e-13,2282.0,2.0);
259 {189} ETHENE + O3P = 0.5HO2 + 0.2RO2_R +
260 0.3C_O2 + 0.491CO+ 0.191HCHO +
261 0.25CCHO + 0.009GLY : ARR(1.04e-11,792.0,0.0);
262 {190} ISOPRENE + OH = 0.907RO2_R +
263 0.093RO2_N + 0.079R2O2+
264 0.624HCHO + 0.23METHACRO +
265 0.32MVK + 0.357ISOPROD : ARR(2.50e-11,-408.0,0.0);
266 {191} ISOPRENE + O3 = 0.266OH +
267 0.066RO2_R + 0.008RO2_N +
268 0.126R2O2+ 0.192MA_RCO3 +
269 0.275CO+ 0.592HCHO + 0.1PROD2 +
270 0.39METHACRO + 0.16MVK +
271 0.204HCOOH + 0.15RCO_OH : ARR(7.86e-15,1912.0,0.0);
272 {192} ISOPRENE + NO3 = 0.187NO2 +
273 0.749RO2_R + 0.064RO2_N +
274 0.187R2O2+ 0.936ISOPROD : ARR(3.03e-12,448.0,0.0);
275 {193} ISOPRENE + O3P = 0.01RO2_N +
276 0.24R2O2+ 0.25C_O2 + 0.24MA_RCO3 +
277 0.24HCHO + 0.75PROD2 : 3.60e-11;
278 {194} TERP + OH = 0.75RO2_R + 0.25RO2_N +
279 0.5R2O2+ 0.276HCHO +
280 0.474RCHO + 0.276PROD2 : ARR(1.83e-11,-449.0,0.0);
281 {195} TERP + O3 = 0.567OH + 0.033HO2 +
282 0.031RO2_R + 0.18RO2_N +
283 0.729R2O2+ 0.123CCO_O2 +
284 0.201RCO_O2 + 0.157CO+
285 0.235HCHO + 0.205RCHO + 0.13ACET +
286 0.276PROD2 + 0.001GLY + 0.031BACL +
287 0.103HCOOH + 0.189RCO_OH : ARR(1.08e-15,821.0,0.0);
288 {196} TERP + NO3 = 0.474NO2 +
289 0.276RO2_R + 0.25RO2_N +
290 0.75R2O2+ 0.474RCHO + 0.276RNO3 : ARR(3.66e-12,-175.0,0.0);
291 {197} TERP + O3P = 0.147RCHO + 0.853PROD2 : 3.27e-11;
292 {198} C2H6 + OH = RO2_R + CCHO : ARR(1.37e-12,498.0,2.0);
293 {199} C3H8 + OH = 0.965RO2_R + 0.035RO2_N +
294 0.261RCHO + 0.704ACET : ARR(0.0,0.0,1.0);
295 {200} C2H2 + OH = 0.603OH + 0.297HO2 +
296 0.1RO2_R + 0.393CO + 0.096HCHO +
297 0.607GLY + 0.297HCOOH : ARR(9.87e-12,671.0,0.0);
298 {201} ALK3 + OH = 0.695RO2_R + 0.07RO2_N +
299 0.559R2O2+ 0.236TBU_O + 0.026HCHO +
300 0.445CCHO + 0.122RCHO + 0.024ACET +
301 0.332MEK : ARR(1.019e-11,434.0,0.0);
302 {202} ALK4 + OH = 0.835RO2_R + 0.143RO2_N +
303 0.936R2O2+ 0.011C_O2 + 0.011CCO_O2 +
304 0.002CO+ 0.024HCHO + 0.455CCHO +
305 0.244RCHO + 0.452ACET + 0.11MEK +
306 0.125PROD2 : ARR(5.946e-12,91.0,0.0);
307 {203} ALK5 + OH = 0.653RO2_R + 0.347RO2_N +
308 0.948R2O2+ 0.026HCHO + 0.099CCHO +
309 0.204RCHO + 0.072ACET + 0.089MEK +
310 0.417PROD2 : ARR(1.112e-11,52.0,0.0);
311 {204} ARO1 + OH = 0.224HO2 + 0.765RO2_R +
312 0.011RO2_N + 0.055PROD2 + 0.118GLY +
313 0.119MGLY + 0.017PHEN + 0.207CRES +
314 0.059BALD + 0.491DCB1 + 0.108DCB2 +
315 0.051DCB3 : ARR(1.81e-12,-355.0,0.0);
316 {205} ARO2 + OH = 0.187HO2 + 0.804RO2_R +
317 0.009RO2_N + 0.097GLY + 0.287MGLY +
318 0.087BACL + 0.187CRES + 0.05BALD +
319 0.561DCB1 + 0.099DCB2 + 0.093DCB3 : (2.640e-11);
320 {206} OLE1 + OH = 0.91RO2_R + 0.09RO2_N +
321 0.205R2O2+ 0.732HCHO + 0.294CCHO +
322 0.497RCHO + 0.005ACET + 0.119PROD2 : ARR(7.095e-12,-451.0,0.0);
323 {207} OLE1 + O3 = 0.155OH + 0.056HO2 +
324 0.022RO2_R + 0.001RO2_N +
325 0.076C_O2 + 0.345CO+ 0.5HCHO +
326 0.154CCHO + 0.363RCHO + 0.001ACET +
327 0.215PROD2 + 0.185HCOOH +
328 0.05CCO_OH + 0.119RCO_OH : ARR(2.617e-15,1640.0,0.0);
329 {208} OLE1 + NO3 = 0.824RO2_R + 0.176RO2_N +
330 0.488R2O2+ 0.009CCHO + 0.037RCHO +
331 0.024ACET + 0.511RNO3 : ARR(4.453e-14,376.0,0.0);
332 {209} OLE1 + O3P = 0.45RCHO + 0.437MEK +
333 0.113PROD2 : ARR(1.074e-11,234.0,0.0);
334 {210} OLE2 + OH = 0.918RO2_R + 0.082RO2_N +
335 0.001R2O2+ 0.244HCHO + 0.732CCHO +
336 0.511RCHO + 0.127ACET + 0.072MEK +
337 0.061BALD + 0.025METHACRO +
338 0.025ISOPROD : ARR(1.743e-11,-384.0,0.0);
339 {211} OLE2 + O3 = 0.378OH + 0.003HO2 +
340 0.033RO2_R + 0.002RO2_N + 0.137R2O2+
341 0.197C_O2 + 0.137CCO_O2 +
342 0.006RCO_O2 + 0.265CO+ 0.269HCHO +
343 0.456CCHO + 0.305RCHO + 0.045ACET +
344 0.026MEK + 0.043PROD2 + 0.042BALD +
345 0.026METHACRO + 0.019MVK +
346 0.073HCOOH + 0.129CCO_OH +
347 0.247RCO_OH : ARR(5.022e-16,461.0,0.0);
348 {212} OLE2 + NO3 = 0.391NO2 + 0.442RO2_R +
349 0.136RO2_N + 0.711R2O2+ 0.03C_O2 +
350 0.079HCHO + 0.507CCHO + 0.151RCHO +
351 0.102ACET + 0.001MEK + 0.015BALD +
352 0.048MVK + 0.321RNO3 : 7.265e-13;
353 {213} OLE2 + O3P = 0.013HO2 + 0.012RO2_R +
354 0.001RO2_N + 0.012CO+ 0.069RCHO +
355 0.659MEK + 0.259PROD2 +
356 0.012METHACRO : 2.085e-11;
357 {214} C2H2 + O3 = 0.5OH + 1.5HO2 +
358 1.5CO + 0.5CO2 : 2.20e-10;
359 {215} C3H6 + OH = 0.984RO2_R + 0.016RO2_N +
360 0.984HCHO + 0.984CCHO + 0.048XC : 2.20e-10;
361 {216} C3H6 + O3 = 0.32OH + 0.06HO2 +
362 0.26C_O2 + 0.51CO + 0.135CO2 + 0.5HCHO +
363 0.5CCHO + 0.185HCOOH + 0.17CCO_OH + 0.07XC: 2.20e-10;
364 {217} C3H6 + NO3 = 0.949RO2_R + 0.051RO2_N +
365 2.693XC + 1.0XN : 2.20e-10;
366 {218} C3H6 + O3P = 0.45RCHO + 0.55MEK +
367 0.55XC: 2.20e-10;
368 {219} SO2 = H2SO4 : 2.20e-10;
369 {220} HO2 = AIR : 7.00e-7;
370 {221} SO2 = AIR : 2.20e-10;
371 {222} H2SO4 = AIR : 2.20e-10;
372 {223} HNO3 = AIR : 2.20e-10;
373 {224} H2O2 = AIR : 2.20e-10;
374 {225} BC = AIR : 7.00e-7;
375 {226} OC = AIR : 7.00e-7;
376 {227} SSF = AIR : 7.00e-7;
377 {228} SSC = AIR : 7.00e-7;
378 {229} PM10 = AIR : 7.00e-7;
379 {230} PM25 = AIR : 7.00e-7;
380 {231} DST1 = AIR : 7.00e-7;
381 {232} DST2 = AIR : 7.00e-7;
382 {233} DST3 = AIR : 7.00e-7;
383 {234} DMS = AIR : 7.00e-7;
384 {235} CO2 = AIR : 7.00e-7;