applications/test/readCHEMKINIII/CHEMKINdata/chem.inp_ch4

   1 ELEMENTS
   2  H   O    C   N  AR
   3 END
   4 SPECIES
   5 H2 O2 OH H H2O O H2O2 HO2
   6 CH4 CO CO2 HCO CH3O CH2OH CH2O CH3 CH2 CH2(S) CH HCCO CH3O2 CH4O2
   7 C2H6 C2H5 C2H4 C2H3 C2H2 C2H CH3CO CH2CO C3H2 C3H3 C3H4 C3H5 C3H6 HCCOH
   8 C2H5OH CH3HCO CH3CHOH CH3OH C4H2 C4H3 CH3OCH3 CH3OCH2 CH3OCH2OOH CH3OCH2OO
   9 CH3OCH2O HCOOCH3 HCOOH CH3OCO
  10 O3 N2 AR C
  11 C3H7 C3H8
  12 THERMO            ! 1995 NASA COMPILATION + EDGAR DATA
  13 CH3O2             L 1/84C   1H   3O   2N   0G   300.000  5000.00               1
  14  0.66812963E 01 0.80057271E-02-0.27188507E-05 0.40631365E-09-0.21927725E-13    2
  15  0.52621851E 03-0.99423847E 01 0.20986490E 01 0.15786357E-01 0.75683261E-07    3
  16 -0.11274587E-07 0.56665133E-11 0.20695879E 04 0.15007068E 02                   4
  17 CH4O2             T12/93C   1H   4O   2N   0G   200.000  6000.000              1
  18  0.61600316E+01 0.10239957E-01-0.36101507E-05 0.57550301E-09-0.34178147E-13    2
  19 -0.17654526E+05-0.61911544E+01 0.49652507E+01 0.92343510E-03 0.34455956E-04    3
  20 -0.44469600E-07 0.17456120E-10-0.16726970E+05 0.29880275E+01                   4
  21 C2H5OH            L 8/88C   2H   6O   1N   0G   200.000  6000.000              1
  22  0.65624365E+01 0.15204222E-01-0.53896795E-05 0.86225011E-09-0.51289787E-13    2
  23 -0.31525621E+05-0.94730202E+01 0.48586957E+01-0.37401726E-02 0.69555378E-04    3
  24 -0.88654796E-07 0.35168835E-10-0.29996132E+05 0.48018545E+01-0.28257829E+05    4
  25 C3H3              BUR 92C   3H   3O   0N   0G   200.000  6000.000              1
  26  6.64175821E+00 8.08587428E-03-2.84787887E-06 4.53525977E-10-2.68879815E-14    2
  27  3.89793699E+04-1.04004255E+01 1.82840766E+00 2.37839036E-02-2.19228176E-05    3
  28  1.00067444E-08-1.38984644E-12 4.01863058E+04 1.38447957E+01 4.16139977E+04    4
  29 C3H4              L12/92C   3H   4O   0N   0G   200.000  6000.000              1
  30  6.31694869E+00 1.11336262E-02-3.96289018E-06 6.35633775E-10-3.78749885E-14    2
  31  2.01174617E+04-1.09718862E+01 2.61307487E+00 1.21223371E-02 1.85405400E-05    3
  32 -3.45258475E-08 1.53353389E-11 2.15415642E+04 1.02503319E+01 2.29622672E+04    4
  33 C3H5              BUR 92C   3H   5O   0N   0G   200.000  6000.000              1
  34  6.54761132E+00 1.33152246E-02-4.78333100E-06 7.71949814E-10-4.61930808E-14    2
  35  1.72714707E+04-9.27486841E+00 3.78794693E+00 9.48414335E-03 2.42343368E-05    3
  36 -3.65604010E-08 1.48592356E-11 1.86261218E+04 7.82822499E+00 2.03259122E+04    4
  37 C3H7            N-L 9/84C   3H   7    0    0G   300.000  5000.000              1
  38  0.77026987E 01 0.16044203E-01-0.52833220E-05 0.76298590E-09-0.39392284E-13    2
  39  0.82984336E 04-0.15480180E 02 0.10515518E 01 0.25991980E-01 0.23800540E-05    3
  40 -0.19609569E-07 0.93732470E-11 0.10631863E 05 0.21122559E 02 0.12087447E 05    4
  41 C4H2              L 2/93C   4H   2O   0N   0G   200.000  6000.000              1
  42  8.66704895E+00 6.71505191E-03-2.35355060E-06 3.73635366E-10-2.21054043E-14    2
  43  5.10016978E+04-2.18002050E+01-4.07132393E-01 5.20775143E-02-9.21138340E-05    3
  44  8.08657403E-08-2.70422080E-11 5.25957367E+04 2.03240223E+01 5.41222513E+04    4
  45 C4H3              L 9/89C   4H   3O   0N   0G   298.150  6000.000              1
  46  0.84762079E+01 0.88782327E-02-0.30328412E-05 0.47358302E-09-0.27716627E-13    2
  47  0.54756540E+05-0.17170551E+02 0.24173247E+01 0.24104782E-01-0.12813470E-04    3
  48 -0.28606237E-08 0.39194527E-11 0.56506476E+05 0.14471107E+02 0.58181574E+05    4
  49 C4H4              L 9/89C   4H   4O   0N   0G   200.000  6000.000              1
  50  0.82948104E+01 0.11994381E-01-0.42624075E-05 0.68306978E-09-0.40680631E-13    2
  51  0.33550866E+05-0.18426826E+02 0.14049083E+01 0.29531073E-01-0.15596302E-04    3
  52 -0.32142002E-08 0.45436937E-11 0.35507830E+05 0.17450183E+02 0.37097268E+05    4
  53 CH3OCH3           L12/92C   2H   6O   1N   0G   200.000  6000.000              1
  54  5.64844183E+00 1.63381899E-02-5.86802367E-06 9.46836869E-10-5.66504738E-14    2
  55 -2.51074690E+04-5.96264939E+00 5.30562279E+00-2.14254272E-03 5.30873244E-05    3
  56 -6.23147136E-08 2.30731036E-11-2.39866295E+04 7.13264209E-01-2.21432171E+04    4
  57 CH3OCH2           T11/82C   2H   5O   1N   0G   300.000  5000.0                1
  58  0.65567484E+01 0.12180723E-01-0.40628420E-05 0.59495830E-09-0.31276214E-13    2
  59 -0.40282515E+04-0.81302772E+01 0.35953999E+01 0.13379216E-01 0.53914910E-05    3
  60 -0.10947097E-07 0.38193320E-11-0.27021975E+04 0.92850365E+01                   4
  61 CH3OCH2OOH        Jan96 C   2H   6O   3N   0G    300.00  3000.00   1000.     0 1
  62  7.66981055E+00 2.35536769E-02-1.15031834E-05 2.84464629E-09-2.79520304E-13    2
  63 -3.96295537E+04-1.39224857E+01 3.05518950E-02 4.90560834E-02-4.43030986E-05    3
  64  2.21548123E-08-4.66587486E-12-3.80282020E+04 2.43189660E+01                   4
  65 CH3OCH2OO         Jan96 C   2H   5O   3N   0G    300.00  3000.00   1000.     0 1
  66  8.06217488E+00 2.05153644E-02-1.00803231E-05 2.50244952E-09-2.46544863E-13    2
  67 -2.19951127E+04-1.59505736E+01 4.74967287E-01 4.68199208E-02-4.55041928E-05    3
  68  2.44627078E-08-5.51108848E-12-2.04517448E+04 2.17234867E+01                   4
  69 CH3OCH2O          Jan96 C   2H   5O   2N   0G    300.00  3000.00   1000.     0 1
  70  5.98450336E+00 1.93302785E-02-9.44575204E-06 2.33651645E-09-2.29626013E-13    2
  71 -2.12266609E+04-7.95685946E+00-1.22386711E-01 3.94270827E-02-3.47990406E-05    3
  72  1.69073231E-08-3.44801024E-12-1.99352987E+04 2.26909497E+01                   4
  73 CH3OCHO           Jan96 C   2H   4O   2N   0G    300.00  3000.00   1000.       1
  74  5.46071782E+00 1.70659166E-02-8.38236448E-06 2.08015776E-09-2.04870146E-13    2
  75 -4.58756417E+04-3.33482124E+00-4.40150386E-01 3.69251939E-02-3.41468832E-05    3
  76  1.73800460E-08-3.70831952E-12-4.46516329E+04 2.61277510E+01                   4
  77 HCOOCH3                 C   2H   4O   2N   0G   300.000  5000.000              1
  78  0.83982000E 01 0.11267000E-01-0.41325000E-05 0.72745000E-09-0.48932000E-13    2
  79 -0.48328000E 05-0.18820000E 02-0.15323000E 01 0.43051000E-01-0.45098000E-04    3
  80  0.26064000E-07-0.63345000E-11-0.45711000E 05 0.31603000E 02                   4
  81 HCOOH             L 8/88H  2.C  1.O  2.   0.G   200.000  6000.000              1
  82  5.69579404E+00 7.72237361E-03-3.18037808E-06 5.57949466E-10-3.52618226E-14    2
  83 -4.81599723E+04-6.01680080E+00 3.23262453E+00 2.81129582E-03 2.44034975E-05    3
  84 -3.17501066E-08 1.20631660E-11-4.67785606E+04 9.86205647E+00-4.55312460E+04    4
  85 CH3OCO                  C   2H   3O   2    0G   300.000  5000.000              1
  86  0.76505900E 01 0.99082000E-02-0.37559700E-05 0.67845900E-09-0.46572100E-13    2
  87 -0.24947700E 05-0.12937300E 02-0.89045900E 00 0.38842600E-01-0.42829300E-04    3
  88  0.25682800E-07-0.63729700E-11-0.22835200E 05 0.29911300E 02                   4
  89 END
  90 REACTIONS
  91 CH4   + O2           = CH3   + HO2        7.900E+13  0.00  56000.
  92 CH4   + H            = CH3   + H2         6.600E+08  1.62  10840. ! 2.200E+04  3.00   8750.
  93 CH4   + OH           = CH3   + H2O        1.600E+06  2.10   2460.
  94 CH4   + O            = CH3   + OH         1.020E+09  1.50   8604.
  95 CH4   + HO2          = CH3   + H2O2       1.800E+11  0.00  18700.
  96 CH3   + HO2          = CH3O  + OH         2.000E+13  0.00      0.
  97 CH3   + O2           = CH3O  + O          2.720E+13  0.00  30900.
  98 CH3   + O2           = CH2O  + OH         3.800E+10  0.00   9000.  ! 3.8
  99 CH3   + CH2O         = CH4   + HCO        5.500E+03  2.82   6000.
 100 CH3   + HCO          = CH4   + CO         1.200E+14  0.00      0.
 101 CH3   + O            = CH2O  + H          8.000E+13  0.00      0.
 102 CH3   + OH           = CH2   + H2O        7.500E+06  2.00   5000.
 103 CH3   + OH           = CH2O  + H2         4.000E+12  0.00      0.
 104 CH3   + H            = CH4                1.900E+36 -7.00   9050.
 105 CH3   + CH3          = C2H6               1.900D+53 -12.0  19400.
 106 !
 107 CH3   + CH3O         = CH4   + CH2O       1.000E+13  0.00      0.
 108 CH3   + CH2OH        = CH4   + CH2O       1.000E+12  0.00      0.
 109 CH3   + C2H5         = CH4   + C2H4       2.000E+13 -0.50      0.
 110 CH3   + C2H4         = CH4   + C2H3       6.620E+00  3.70   9482.
 111 CH3   + C2H3         = CH4   + C2H2       1.000E+12  0.00      0.
 112 CH3   + C2H2         = CH4   + C2H        1.800E+11  0.00  17270.
 113 CH3   + CH3          = C2H4  + H2         1.000E+14  0.00  31000.
 114 CH3   + M            = CH2   + H     + M  1.000E+16  0.00  90600.
 115 CH3   + HCO          = CH2   + CH2O       2.000E+14  0.00      0.
 116 CH2   + H2           = CH3   + H          5.000E+05  2.00   7230.
 117 CH2   + CH3          = C2H4  + H          4.000E+13  0.00      0.
 118 !
 119 CH2(S)+ CH3          = C2H4  + H          3.000E+13  0.00   -570.
 120 CH2(S)+ H2           = CH3   + H          8.000E+13  0.00      0.
 121 CH2(S)+ CH4          = CH3   + CH3        4.000E+12  0.00   -570.
 122 CH2(S)+ C2H6         = CH3   + C2H5       4.000E+12  0.00   -550.
 123 CH2(S)+ C2H2         = C3H3  + H          3.000E+13  0.00      0.
 124 CH2(S)+ N2           = CH2   + N2         1.500E+13  0.00    600.
 125 CH2(S)+ AR           = CH2   + AR         9.000E+12  0.00    600.
 126 CH2(S)+ CO2          = CH2   + CO2        7.000E+12  0.00      0.
 127 CH2(S)+ CO2          = CH2O  + CO         1.400E+11  0.00   1000.
 128 CH2(S)+ H2O          = CH2   + H2O        3.000E+13  0.00      0.
 129 CH2(S)+ O2           = CO    + OH    + H  2.800E+12  0.00   -500.
 130 CH2(S)+ O2           = CO    + H2O        1.200E+12  0.00   -500.
 131 CH2(S)+ H            = CH    + H2         3.000E+13  0.00      0.
 132 CH2(S)+ O            = CO    + H2         3.000E+13  0.00      0.
 133 !
 134 CH2OH + H            = CH3   + OH         1.000E+14  0.00      0.
 135 CH3O  + H            = CH3   + OH         1.000E+14  0.00      0.
 136 CH3O  + M            = CH2O  + H     + M  1.000E+14  0.00  25000.
 137 CH2OH + M            = CH2O  + H     + M  1.000E+14  0.00  25000.
 138 CH3O  + H            = CH2O  + H2         2.000E+13  0.00      0.
 139 CH2OH + H            = CH2O  + H2         2.000E+13  0.00      0.
 140 CH3O  + OH           = CH2O  + H2O        1.000E+13  0.00      0.
 141 CH2OH + OH           = CH2O  + H2O        1.000E+13  0.00      0.
 142 CH3O  + O            = CH2O  + OH         1.000E+13  0.00      0.
 143 CH2OH + O            = CH2O  + OH         1.000E+13  0.00      0.
 144 CH3O  + O2           = CH2O  + HO2        6.300E+10  0.00   2600.    ! 6.3
 145 CH2OH + O2           = CH2O  + HO2        1.480E+13  0.00   1500.
 146 !CH2   + H            = CH    + H2         1.000E+18 -1.56      0.
 147 CH2   + OH           = CH    + H2O        1.130E+07  2.00   3000.
 148 CH2   + OH           = CH2O  + H          2.500E+13  0.00      0.
 149 CH2   + CH2          = C2H2  + H2         4.000E+13  0.00      0.
 150 CH2   + HCCO         = C2H3  + CO         3.000E+13  0.00      0.
 151 CH    + H2           = H     + CH2        1.107E+08  1.79   1670.
 152 CH    + O2           = HCO   + O          6.300E+13  0.00      0.
 153 CH    + O            = CO    + H          5.700E+13  0.00      0.
 154 CH    + OH           = HCO   + H          3.000E+13  0.00      0.
 155 CH    + CO2          = HCO   + CO         3.400E+12  0.00    690.
 156 CH    + H2O          = CH2O  + H          1.170E+15 -0.75      0.
 157 CH    + CH2O         = CH2CO + H          9.460E+13  0.00   -515.
 158 CH    + C2H2         = C3H2  + H          1.000E+14  0.00      0.
 159 CH    + CH2          = C2H2  + H          4.000E+13  0.00      0.
 160 CH    + CH3          = C2H3  + H          3.000E+13  0.00   -400.
 161 CH    + CH4          = C2H4  + H          3.000E+13  0.00      0.
 162 CH2   + O            = CO    + H     + H  5.000E+13  0.00      0.
 163 CH2   + O            = HCO   + H          8.000E+13  0.00      0.
 164 CH2   + O2           = CO2   + H     + H  1.600E+12  0.00   1000.
 165 CH2   + O2           = CH2O  + O          5.000E+13  0.00   9000.
 166 CH2   + O2           = CO2   + H2         6.900E+11  0.00    500.
 167 CH2   + O2           = HCO   + OH         4.300E+10  0.00   -500.
 168 CH2O  + OH           = HCO   + H2O        3.430E+09  1.18   -447.
 169 CH2O  + H            = HCO   + H2         2.190E+08  1.77   3000.
 170 CH2O  + M            = HCO   + H     + M  3.310E+16  0.00  81000.
 171 CH2O  + O            = HCO   + OH         1.800E+13  0.00   3080.
 172 CH2O  + O2           = HCO   + HO2        6.200E+13  0.00  39000.
 173 CH2O  + HO2          = HCO   + H2O2       1.000E+12  0.00   9000.
 174 CH2O  + HO2          = HCOOH + OH         1.000E+13  0.00  14900.
 175 !
 176 HCOOH + H            = H     + CO2  + H2  3.060E+10  1.00   3200.
 177 HCOOH + O            = H     + CO2  + OH  5.360E+11  0.60   2900.
 178 HCOOH + OH           = H     + CO2  + H2O 2.500E+11  0.00      0.
 179 HCOOH + HO2          = H2O2  + CO2  + H   2.500E+11  0.00      0.
 180 HCOOH + CH3          = CH4   + CO2  + H   1.100E-03  4.90   3480.
 181 HCOOH + CH3OCH2      = CH3OCH3 + CO2 + H  1.100E-03  4.90   3480.
 182 !
 183 HCO   + OH           = H2O   + CO         1.000E+14  0.00      0.
 184 !HCO   + M            = H     + CO    + M  2.500E+14  0.00  16802.
 185 HCO   + H2O          = H     + CO   + H2O 2.244E+18 -1.00  17000.
 186 HCO   + M            = H     + CO    + M  1.870E+17 -1.00  17000.
 187 H2/2.00/ H2O/ .00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/
 188 HCO   + H            = CO    + H2         1.190E+13  0.25      0.
 189 HCO   + O            = CO    + OH         3.000E+13  0.00      0.
 190 HCO   + O            = CO2   + H          3.000E+13  0.00      0.
 191 HCO   + O2           = HO2   + CO         3.300E+13 -0.40      0.
 192 HCO   + HCO          = CH2O  + CO         3.000E+13  0.00      0.
 193 HCO   + HCO          = H2    + CO   + CO  3.000E+12  0.00      0.
 194 CO    + O    + M     = CO2   + M          6.170E+14  0.00   3000.
 195 H2/2.00/ O2/6.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/3.50/ C2H6/3.00/ AR/0.50/
 196 CO    + OH           = CO2   + H          1.510E+07  1.30   -758.
 197 CO    + O2           = CO2   + O          1.600E+13  0.00  41000.
 198 HO2   + CO           = CO2   + OH         5.800E+13  0.00  22934.
 199 C2H6  + CH3          = C2H5  + CH4        5.500E-01  4.00   8300.
 200 C2H6  + H            = C2H5  + H2         5.400E+02  3.50   5210.
 201 C2H6  + O            = C2H5  + OH         3.000E+07  2.00   5115.
 202 C2H6  + OH           = C2H5  + H2O        8.700E+09  1.05   1810.
 203 C2H4  + H            = C2H3  + H2         1.100E+14  0.00   8500.
 204 C2H4  + O            = CH3   + HCO        1.600E+09  1.20    746.
 205 C2H4  + OH           = C2H3  + H2O        2.020E+13  0.00   5955.
 206 H     + C2H4         = C2H5               2.600E+43 -9.25  52580.
 207 C2H5  + H            = CH3   + CH3        1.000E+14  0.00      0.
 208 C2H5  + O2           = C2H4  + HO2        8.430E+11  0.00   3875.
 209 C2H2  + O            = CH2   + CO         1.020E+07  2.00   1900.
 210 C2H2  + O            = HCCO  + H          1.020E+07  2.00   1900.
 211 H2    + C2H          = C2H2  + H          4.090E+05  2.39    864.
 212 C2H3                 = C2H2  + H          4.600E+40 -8.80  46200.
 213 C2H3  + H            = C2H2  + H2         4.000E+13  0.00      0.
 214 C2H3  + O            = CH2CO + H          3.000E+13  0.00      0.
 215 C2H3  + O2           = CH2O  + HCO        4.000E+12  0.00   -250.
 216 C2H3  + O2           = C2H2  + HO2        1.580E+13  0.00  10060.
 217 C2H3  + OH           = C2H2  + H2O        5.000E+12  0.00      0.
 218 C2H3  + CH2          = C2H2  + CH3        3.000E+13  0.00      0.
 219 C2H3  + C2H          = C2H2  + C2H2       3.000E+13  0.00      0.
 220 C2H3  + CH           = CH2   + C2H2       5.000E+13  0.00      0.
 221 OH    + C2H2         = C2H   + H2O        3.370E+07  2.00  14000.
 222 OH    + C2H2         = HCCOH + H          5.040E+05  2.30  13500.
 223 OH    + C2H2         = CH2CO + H          2.180E-04  4.50  -1000.
 224 OH    + C2H2         = CH3   + CO         4.830E-04  4.00  -2000.
 225 C2H2  + O            = C2H   + OH         3.160E+15 -0.60  15000.
 226 HCCOH + H            = CH2CO + H          1.000E+13  0.00      0.
 227 !
 228 CH2CO + O            = CO2   + CH2        1.750E+12  0.00   1350.
 229 CH2CO + O            = HCO   + HCO        2.300E+13  0.00   2300.
 230 CH2CO + H            = CH3   + CO         1.130E+13  0.00   3428.
 231 CH2CO + H            = HCCO  + H2         5.000E+13  0.00   8000.
 232 CH2CO + O            = HCCO  + OH         1.000E+13  0.00   8000.
 233 CH2CO + OH           = HCCO  + H2O        7.500E+12  0.00   2000.
 234 CH2CO + M            = CH2   + CO   + M   3.000E+14  0.00  70980.
 235 C2H   + O2           = CO    + CO   + H   5.000E+13  0.00   1500.
 236 HCCO  + H            = CH2(S)+ CO         1.000E+14  0.00      0.
 237 HCCO  + O            = H     + CO   + CO  1.000E+14  0.00      0.
 238 HCCO  + O2           = OH    + CO   + CO  1.600E+12  0.00    854.
 239 HCCO  + CH           = C2H2  + CO         5.000E+13  0.00      0.
 240 HCCO  + HCCO         = C2H2  + CO   + CO  1.600E+12  0.00    854.
 241 C2H   + O            = CH    + CO         5.000E+13  0.00      0.
 242 C2H   + OH           = HCCO  + H          2.000E+13  0.00      0.
 243 C3H2  + O2           = HCCO  + HCO        1.000E+13  0.00      0.
 244 C3H3  + O2           = CH2CO + HCO        3.000E+10  0.00   2868.
 245 C3H3  + O            = CH2O  + C2H        2.000E+13  0.00      0.
 246 C3H3  + OH           = C3H2  + H2O        2.000E+13  0.00      0.
 247 C2H2  + O2           = HCCO  + OH         2.000E+08  1.50  30100.
 248 C2H2  + M            = C2H   + H     + M  4.200E+16  0.00 107000.
 249 C2H4  + M            = C2H2  + H2    + M  1.500E+15  0.00  55800.
 250 H2    + O2           = OH    + OH         1.700E+13  0.00  47780.
 251 H2    + OH           = H2O   + H          1.170E+09  1.30   3626.
 252 O     + OH           = O2    + H          8.000E+14 -0.60      0.
 253 !H     + O2           =  O    + OH         8.300E+13  0.00  14413.
 254 O     + H2           = OH    + H          5.060E+04  2.67   6290.
 255 H     + O2   + M     = HO2   + M          3.610E+17 -0.72      0.
 256   H2O/21./  CO2/5.0/  H2/3.3/  CO/2.0/ AR/0.0/
 257 H     + O2   +    AR = HO2   + AR         7.000E+17 -0.80     0.
 258 OH    + HO2          = H2O   + O2         2.890E+13  0.00    497.
 259 H     + HO2          = OH    + OH         1.700E+14  0.00    874.
 260 O     + HO2          = O2    + OH         1.400E+13  0.00   1073.
 261 OH    + OH           = O     + H2O        6.000E+08  1.30      0.
 262 H     + H    + M     = H2    + M          1.000E+18 -1.00      0.
 263   H2O/0./   H/2./  H2/0./ CO2/0./ AR/0.5/
 264 H     + H    + H2    = H2    + H2         9.200E+16 -0.60      0.
 265 H     + H    + H2O   = H2    + H2O        6.000E+19 -1.25      0.
 266 H     + H    + CO2   = H2    + CO2        5.490E+20 -2.00      0.
 267 H     + OH   + M     = H2O   + M          1.600E+22 -2.00      0.
 268   H2/0.73/ H2O/3.65/ CH4/2.00/ C2H6/3.00/ AR/0.38/
 269 H     + O    + M     = OH    + M          5.000E+17 -1.00      0.
 270   H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.50/
 271 O     + O    + M     = O2    + M          1.200E+17 -1.00      0.
 272   H2/ 2.40/ H2O/15.40/ CH4/ 2.00/ CO/ 1.75/ CO2/ 3.60/ C2H6/ 3.00/ AR/ 0.50/
 273 H     + HO2          = H2    + O2         4.280E+13  0.00   1411.
 274 HO2   + HO2          = H2O2  + O2         3.020E+12  0.00   1390.  ! 1.300E+11     .000   -1630.00
 275 H2O2  + M            = OH    + OH    + M  1.200E+17  0.00  45500.
 276      AR/0.5/
 277 H2O2  + H            = HO2   + H2         4.790E+13  0.00   7950.
 278 H2O2  + OH           = H2O   + HO2        1.000E+13  0.00   1800.
 279 H     + HO2          = O     + H2O        3.100E+10  0.00   1720.
 280 O     + OH   + M     = HO2   + M          6.400E+15  0.00      0.
 281      AR/0.5/
 282 H2O2  + H            = H2O   + OH         1.000E+13  0.00   3590.
 283 H2O2  + O            = H2O   + O2         8.400E+11  0.00   4260.
 284 H2O2  + O            = OH    + HO2        2.000E+13  0.00   5900.
 285 H2    + HO2          = H2O   + OH         6.500E+11  0.00  18800.
 286 C2H6  + CH           = H     + C3H6       1.100E+14  0.00   -263.
 287 C3H6  + O            = CH3CO + CH3        5.000E+12  0.00    454.
 288 C3H6  + O            = C2H5  + HCO        1.500E+12  0.00      0.
 289 CH3CO + H            = CH2CO + H2         2.000E+13  0.00      0.
 290 CH3CO + O            = CH3   + CO2        2.000E+13  0.00      0.
 291 CH3CO + CH3          = C2H6  + CO         5.000E+13  0.00      0.
 292 CH3CO                = CH3   + CO         2.300E+26 -5.00  17970.
 293 !C2H3  + CH3  + M     = C3H6  + M          5.000E+10  0.00      0.
 294 CH3   + C2H3         = C3H6               2.000E+13  0.00      0.
 295 CH3   + C2H2         = C3H5               6.000E+11  0.00  16000.
 296 C2H5  + C3H5         = C2H4  + C3H6       4.000E+11  0.00      0.
 297 C2H3  + C3H6         = C2H4  + C3H5       3.160E+12  0.00  31000.
 298 C3H5  + H            = C3H6               2.000E+13  0.00      0.
 299 C2H6  + O2           = C2H5  + HO2        1.000E+13  0.00  48960.
 300 C2H4  + O2           = C2H3  + HO2        4.200E+13  0.00  57590.
 301 C2H5  + HO2          = C2H4  + H2O2       3.000E+11  0.00      0.
 302 !
 303 O3    + M            = O2    + O     + M  3.000E+14  0.00  22180.
 304 O3    + O            = O2    + O2         1.000E+13  0.00   4570.
 305 O3    + H            = O2    + OH         1.000E+14  0.00    890.
 306 O3    + OH           = HO2   + O2         1.000E+12  0.00   1848.
 307 O3    + HO2          = OH    + O2    + O2 1.000E+13  0.00  11000.
 308 !
 309 CH3OH                = CH2OH + H          3.700E+15  0.00  96700.
 310 CH3OH                = CH3O  + H          4.500E+15  0.00  96700.
 311 CH3OH                = CH3   + OH         3.800E+15  0.00  91700.
 312 CH3OH + O2           = CH2OH + HO2        4.050E+13  0.0   44906.
 313 CH3OH + H            = CH2OH + H2         1.700E+07  2.10   4870.
 314 CH3OH + H            = CH3O  + H2         4.200E+06  2.10   4870.
 315 CH3OH + O            = OH    + CH2OH      3.880E+05  2.50   3100.
 316 CH3OH + O            = OH    + CH3O       1.300E+05  2.50   5000.
 317 CH3OH + OH           = CH2OH + H2O        1.440E+06  2.00   -840.
 318 CH3OH + OH           = CH3O  + H2O        6.300E+06  2.00   1500.
 319 CH3OH + HO2          = CH2OH + H2O2       5.200E+13  0.00  19360.
 320 CH3OH + CH3          = CH2OH + CH4        3.000E+07  1.50   9940.
 321 CH3OH + CH3          = CH3O  + CH4        1.000E+07  1.50   9940.
 322 CH3OH + CH3O         = CH3OH + CH2OH      3.00E+11   0.0    4000.
 323 CH3O  + CH3O         = CH3OH + CH2O       1.200E+12  0.0       0.
 324 CH2OH + CH2OH        = CH3OH + CH2O       1.200E+12  0.0       0.
 325 CH2OH + HCO          = CH3OH + CO         1.200E+12  0.0       0.
 326 !
 327 C2H5OH               = CH3     + CH2OH    3.020E+18  0.00  75470.
 328 C2H5OH + O2          = CH3CHOH + HO2      4.000E+10  0.00  50000.
 329 C2H5OH + OH          = CH3CHOH + H2O      3.020E+13  0.00   5960.
 330 C2H5OH + H           = CH3CHOH + H2       4.360E+12  0.00   4570.
 331 C2H5OH + O           = CH3CHOH + OH       6.760E+12  0.00   1510.
 332 C2H5OH + HO2         = CH3CHOH + H2O2     6.310E+12  0.00  15000.
 333 C2H5OH + CH3         = CH3CHOH + CH4      4.000E+12  0.00   9690.
 334 !
 335 CH3CHOH + M          = CH3HCO  + H   + M  5.000E+13  0.00  21850.
 336 CH3CHOH + O2         = CH3HCO  + HO2      1.000E+13  0.0    5560.
 337 C2H5OH  + H          = C2H5    + H2O      5.250E+12  0.00   5000.
 338 CH3HCO               = CH3     + HCO      7.080E+15  0.00  81760.
 339 CH3HCO               = CH3CO   + H        5.000E+14  0.00  87860.
 340 CH3HCO  + O2         = CH3CO   + HO2      2.000E+13  0.50  42200.
 341 CH3HCO  + H          = CH3CO   + H2       4.000E+13  0.00   4200.
 342 CH3HCO  + OH         = CH3CO   + H2O      1.000E+13  0.00      0.
 343 CH3HCO  + O          = CH3CO   + OH       5.000E+12  0.00   1790.
 344 CH3HCO  + CH3        = CH3CO   + CH4      1.700E+12  0.00   8430.
 345 CH3HCO  + HO2        = CH3CO   + H2O2     1.700E+12  0.00  10700.
 346 C2H2    + C2H2       = C4H3    + H        2.000E+12  0.00  45900.
 347 C4H3    + M          = C4H2    + H  + M   1.000E+16  0.00  59700.
 348 C4H2    + O          = C3H2    + CO       1.200E+12  0.00      0.
 349 C2H2    + C2H        = C4H2    + H        4.000E+13  0.00      0.
 350 C3H4    + O          = CH2O    + C2H2     1.000E+12  0.00      0.
 351 C3H4    + OH         = CH2O    + C2H3     1.000E+12  0.00      0.
 352 C3H4    + O          = HCO     + C2H3     1.000E+12  0.00      0.
 353 C3H4    + OH         = HCO     + C2H4     1.000E+12  0.00      0.
 354 C3H6    + O          = CH2O    + C2H4     5.900E+13  0.00      0.
 355 C3H6    + OH         = CH3     + CH3HCO   7.080E+12  0.00      0.
 356 C3H6    + OH         = C3H5    + H2O      4.000E+12  0.00      0.
 357 C3H6    + OH         = C2H5    + CH2O     8.000E+12  0.00      0.
 358 C3H6    + H          = C3H5    + H2       5.000E+12  0.00   1500.
 359 C3H6    + CH3        = C3H5    + CH4      1.000E+11  0.00   8500.
 360 C3H6    + C2H5       = C3H5    + C2H6     1.000E+11  0.00   9200.
 361 C3H5                 = C3H4    + H        4.000E+13  0.00  70000.
 362 C3H5    + O2         = C3H4    + HO2      6.020E+11  0.00  10000.
 363 C3H5    + H          = C3H4    + H2       1.000E+13  0.00      0.
 364 C3H5    + CH3        = C3H4    + CH4      1.000E+12  0.00      0.
 365 !
 366 CH3     + O2         = CH3O2              9.020E+58 -15.0  17204.
 367 CH3O2   + HO2        = CH4O2   + O2       4.630E+10   0.0  -2583.
 368 CH3O2   + CH4        = CH4O2   + CH3      1.810E+11   0.0  18480.
 369 CH3O2   + CH3        = CH3O    + CH3O     2.410E+13   0.0      0.
 370 CH3O2   + O          = CH3O    + O2       3.610E+13   0.0      0.
 371 CH3O2   + H          = CH3O    + OH       9.640E+13   0.0      0.
 372 CH3O2   + OH         = CH3OH   + O2       6.030E+13   0.0      0.
 373 CH3O2   + CH2O       = CH4O2   + HCO      1.000E+12   0.0  11665.
 374 CH3O2   + CH3OH      = CH4O2   + CH2OH    1.800E+12   0.0  13712.
 375 CH3O2   + C2H6       = CH4O2   + C2H5     2.950E+11   0.0  14944.
 376 CH4O2                = CH3O    + OH       4.000E+15   0.0  42924.
 377 CH4O2   + OH         = CH3O2   + H2O      8.200E+11   0.0   -258.
 378 !
 379 CH3OCH3 + H          = CH3OCH2 + H2       8.400E+07  2.00   7700.
 380 CH3OCH3 + O          = CH3OCH2 + OH       6.540E+06  2.40   5500.
 381 CH3OCH3 + OH         = CH3OCH2 + H2O      6.560E+09  1.00   1590.
 382 CH3OCH3 + HO2        = CH3OCH2 + H2O2     4.200E+12  0.00  13875.
 383 CH3OCH3 + CH3O       = CH3OCH2 + CH3OH    2.600E+12  0.00   7000.
 384 CH3OCH3 + O2         = CH3OCH2 + HO2      4.100E+13  0.00  44906.
 385 CH3OCH3 + CH3        = CH3OCH2 + CH4      1.950E+12  0.00  11600.
 386 CH3OCH3              = CH3+CH3O           2.620E+16  0.0   82202.
 387 CH3OCH3              = CH3OCH2 + H        2.588E+16  .265 104300.
 388 CH3OCH2              = CH3+CH2O           3.300E+14  0.0   31000.      !  4.3
 389 CH3OCH2 + CH3O       = CH3OCH3 + CH2O     6.030E+13  0.0       0.
 390 CH3OCH2 + O2         = CH3OCH2OO          2.000E+42 -10.3   6080.
 391 CH3OCH2 + O2         = HCOOCH3 + OH       5.480E+13  0.0    8370.
 392 CH3OCH2 + HO2        = CH2O   + CH3O + OH 3.000E+12  0.0       0.
 393 CH3OCH2 + H2O2       = CH2O  + CH3O + H2O 3.000E+12  0.0       0.
 394 CH3OCH2OO + CH3OCH3  = CH3OCH2OOH+CH3OCH2 1.200E+12  0.0   14000.      !  2.2
 395 CH3OCH2OOH           = CH3OCH2O  + OH     8.200E+08  3.65  34000.
 396 CH3OCH2O             = CH3O      + CH2O   4.000E+14  0.0   15600.
 397 CH3OCH2O + O2        = HCOOCH3 + HO2      2.000E+12  0.0    6000.
 398 CH3OCH2OOH           = CH2O + CH2O + H2O  8.800E+12  0.0   16000.
 399 CH3OCH3   + CH3O2    = CH3OCH2   + CH4O2  1.500E+13  0.0   13700.      !  2.0
 400 CH3O2     + CH3O2    = CH3O + CH3O + O2   6.300E+10  0.0    -600.
 401 CH3O2     + CH3O2    = CH3OCH2O + HO2     6.300E+10  0.0    -600.
 402 ! new termination reactions
 403 CH3OCH2O  + CH3      = CH4     + HCOOCH3  6.000E+13  0.0       0.
 404 CH3OCH2O  + H        = H2      + HCOOCH3  6.000E+13  0.0       0.
 405 CH3OCH2O  + HO2      = H2O2    + HCOOCH3  6.000E+13  0.0       0.
 406 CH3OCH2O  + O        = OH      + HCOOCH3  6.000E+13  0.0       0.
 407 CH3OCH2O  + OH       = H2O     + HCOOCH3  6.000E+13  0.0       0.
 408 CH3OCH2O  + C2H5     = C2H6    + HCOOCH3  6.000E+13  0.0       0.
 409 CH3OCH2O  + CH3OCH2  = CH3OCH3 + HCOOCH3  6.000E+13  0.0       0.
 410 CH3OCH2O  + CH3O     = CH3OH   + HCOOCH3  6.000E+13  0.0       0.
 411 HCOOCH3              = CH4     + CO2      6.000E+09  0.0   48520.
 412 HCOOCH3              = CH3O    + HCO      6.200E+09 1.61  102580.
 413 HCOOCH3   + O        = CH3OCO  + OH       5.360E+11  0.6    2900.
 414 HCOOCH3   + H        = CH3OCO  + H2       1.620E+08  1.6    1980.
 415 HCOOCH3   + OH       = CH3OCO  + H2O      1.200E+09  1.3    -280.
 416 HCOOCH3   + HO2      = CH3OCO  + H2O2     4.000E+12  0.0   12060.
 417 HCOOCH3   + CH3      = CH3OCO  + CH4      9.900E-03  4.5    3420.
 418 HCOOCH3   + CH3O     = CH3OCO  + CH3OH    1.020E+11  0.0    2980.
 419 HCOOCH3   + CH3OCH2  = CH3OCO  + CH3OCH3  1.100E-03  4.9    3480.
 420 CH3OCO               = CO2 +  CH3         1.000E+11  1.1     860.
 421 !
 422 H         + CH       = C         + H2     1.100E+14  0.0       0.
 423 C         + O2       = O         + CO     5.800E+13  0.0     576.
 424 C         + CH2      = H         + C2H    5.000E+13  0.0       0.
 425 C         + CH3      = H         + C2H2   5.000E+13  0.0       0.
 426 !
 427 CH3+C2H5(+M)=C3H8(+M)                  .9430E+13     .000       .00
 428      LOW/ 2.710E+74  -16.82  13065.0 /
 429      TROE/ .1527  291.0  2742.0  7748.0 /
 430 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
 431 O+C3H8=OH+C3H7                         1.930E+05    2.680   3716.00
 432 H+C3H8=C3H7+H2                         1.320E+06    2.540   6756.00
 433 OH+C3H8=C3H7+H2O                       3.160E+07    1.800    934.00
 434 C3H7+H2O2=HO2+C3H8                     3.780E+02    2.720   1500.00
 435 CH3+C3H8=C3H7+CH4                      0.903E+00    3.650   7154.00
 436 CH3+C2H4(+M)=C3H7(+M)                  2.550E+06    1.600   5700.00
 437       LOW/ 3.00E+63  -14.6  18170./
 438       TROE/ .1894  277.0  8748.0  7891.0 /
 439 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
 440 O+C3H7=C2H5+CH2O                       9.640E+13     .000       .00
 441 H+C3H7(+M)=C3H8(+M)                    3.613E+13     .000       .00
 442       LOW/ 4.420E+61  -13.545  11357.0/
 443       TROE/ .315  369.0  3285.0  6667.0 /
 444 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
 445 H+C3H7=CH3+C2H5                        4.060E+06    2.190    890.00
 446 OH+C3H7=C2H5+CH2OH                     2.410E+13     .000       .00
 447 HO2+C3H7=O2+C3H8                       2.550E+10    0.255   -943.00
 448 HO2+C3H7=OH+C2H5+CH2O                  2.410E+13     .000       .00
 449 CH3+C3H7=2C2H5                         1.927E+13   -0.320       .00
 450 END